28974-20-1Relevant academic research and scientific papers
A mild and efficient flow procedure for the transfer hydrogenation of ketones and aldehydes using hydrous zirconia
Battilocchio, Claudio,Hawkins, Joel M.,Ley, Steven V.
supporting information, p. 2278 - 2281 (2013/06/05)
A flow chemistry Meerwein-Ponndorf-Verley (MPV) reduction procedure using partially hydrated zirconium oxide via a machine-assisted approach is reported. The heterogeneous reductive system could be applied to a wide range of functionalized substrates, allowing clean and fast delivery of the alcohol products within a few minutes (6-75 min). In three examples the system was scaled to deliver 50 mmol of product.
A NEW COMBINED OXIDIZING REAGENT SYSTEM, Fe(CH3CN)6(3+)-IO4(1-): OXIDATION OF PARAFFIN HYDROCARBONS
Kotani, Eiichi,Kobayashi, Shigeki,Ishii, Yoko,Tobinaga, Seisho
, p. 4680 - 4684 (2007/10/02)
Combined oxidizing reagent systems of Fe(AN)6ClO4)3 ( AN = acetonitrile ) with halogen oxyacids were investigated.In particular, reactions of paraffin hydrocarbons with a combined reagent system of Fe(AN)6(3+) were explored because of the high reactivity of this system in the oxidation of adamantane ( Table 1 ).Oxidation of bornane, norbornane, cyclohexane, and n-hexane gave the corresponding acetamides and acetates ( Tabla II ).These results shows that the title reagent system can efficiently oxidize organic substrates which have onset potentials of anodic current of ca. 2.7 V vs. saturated calomel electrode.Keywords - oxidation; paraffin hydrocarbon; combined reagent system; hexakisacetonitrile iron(III) perchlorate; halogen oxyacid; sodium periodate
