70897-07-3Relevant articles and documents
Method for producing camphorquinone by taking byproduct generated in camphor synthesis process as raw material
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Paragraph 0046; 0047, (2019/09/14)
The invention provides a method for producing camphorquinone by taking a byproduct generated in the camphor synthesis process as a raw material, belonging to the technical field of organic synthesis.The byproduct 3-camphene ester generated in the synthesis process of camphor is used as a starting material to prepare high-purity camphorquinone through refining, saponification, dehydrogenation, condensation, hydrolysis and recrystallization steps. The method has the beneficial effects that the value of the byproduct generated in the camphor synthesis process is used, industrial wastes are reduced, wastes are changed into valuables, environmental pressure is reduced, a brand-new path for the synthesis of the camphorquinone is provided, no heavy metals are used in all process steps, truly nontoxic chemical synthesis of the camphorquinone is realized, and the method is an economic and environment-friendly production process.
Effective oxidation of benzylic and aliphatic alcohols with hydrogen peroxide catalyzed by a manganese(III) Schiff-base complex under solvent-free conditions
Mardani, Hamid R.,Golchoubian, Hamid
, p. 2349 - 2352 (2007/10/03)
A variety of alcohols were oxidized efficiently into the corresponding ketones and carboxylic acids in excellent yields with hydrogen peroxide using a manganese(III) Schiff-base complex as a catalyst under solvent-free and mild conditions. The oxidation procedure is very simple and the products are easily isolated in excellent yields.
OXIDATION OF NON-ACTIVATED C-H BONDS IN HYDROCARBONS AND STEROIDS
Linz, T.,Schaefer, H. J.
, p. 6581 - 6582 (2007/10/02)
CrO3 in CH2Cl2/CH3COOH/(CH3CO)2O oxidizes hydrocarbons to alcohols and ketones, 5α-androstane and 3β-acetoxy-5α-androstane are converted to 5α-androst-14-en-16-ones.
The S,S-Acetal to Carbonyl Transformation using the Soft NO+ or Cl+ Species
El-Wassimy, M.T.M.,Joergensen, K.A.,Lawesson S.-O.
, p. 2201 - 2204 (2007/10/02)
A series of S,S-acetals (spiro-1,3-dithiolanes, 1,3-dithiolanes, and S,S-dibenzyl acetals) have been converted into the corresponding carbonyl compounds by sodium nitrite in aqueous solutions (NO+, H2ONO+, ClNO) or with t-butyl hypochlorite (Cl+) in anhydrous CCl4.Mechanisms for these transformations are suggested, based on the Hard and Soft Acids and Bases (HSAB) principle.