28984-20-5

Basic information

• Product Name: BIS(DITHIOBENZIL) NICKEL
• Synonyms: 2-diphenyl-1,2-ethenedithiolato(2-)-s,s’]-bis[(sp-4-1)-nicke;bis[1,2-diphenyl-1,2-ethenedithiolato(2-)-κS,κS’],(SP-4-1)-Nickel;BIS(DITHIOBENZIL) NICKEL;BIS(DITHIOBENZIL)NICKEL(II);bis[stilbene-alpha,beta-dithiolato(2-)]nickel;bis[1,2-diphenyl-1,2-ethenedithiolato(2-)-κS,κS'], (SP-4-1)-Nickel 2-diphenyl-1,2-ethenedithiolato(2-)-s,s']- bis[ (sp-4-1)-nicke bisdithiobenzilnickel;bis(dithiobenzil)nickel(Ⅱ);Bis[1,2-diphenyl-1,2-ethenedi
• CAS NO: 28984-20-5
• Molecular Formula: C₂₈H₂₀NiS₄
• Molecular Weight: 543.41
• EINECS: 249-353-4
• Product Categories: Acceptors (Charge Transfer Complexes);Charge Transfer Complexes for Organic Metals;Classes of Metal Compounds;Functional Materials;Metal Dithiolenes;Ni (Nickel) Compounds;Transition Metal Compounds
• Mol File: 28984-20-5.mol
• Article Data: 8

Chemical Properties

• Melting Point: 292～293℃
• Boiling Point: 364.5 °C at 760 mmHg
• Flash Point: 174.2 °C
• Appearance: /
• Density: 1.44 g/cm3
• Vapor Pressure: 3.52E-05mmHg at 25°C
• Storage Temp.: Inert atmosphere,Room Temperature
• CAS DataBase Reference: BIS(DITHIOBENZIL) NICKEL(CAS DataBase Reference)
• NIST Chemistry Reference: BIS(DITHIOBENZIL) NICKEL(28984-20-5)
• EPA Substance Registry System: BIS(DITHIOBENZIL) NICKEL(28984-20-5)

Safety Data

• Hazardous Substances Data: 28984-20-5(Hazardous Substances Data)

Usage

Uses

Bis(dithiobenzil) Nickel is a stable material which is near-IR absorbing, and has been used to fabricate organic photovoltaic cells.

InChI:InChI=1/2C14H10S2.Ni/c2*15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;/h2*1-10H;

Upstream product

• 63936-19-6 bis(tetraphenylcyclopentadienone) nickel 
• 13463-39-3 tetracarbonyl nickel 
• 15857-57-5 tetraphosphorus decasulfide 
• 119-53-9 2-hydroxy-2-phenylacetophenone 
• 77097-47-3 cis-1,2-Diphenylethylen-1,2-dithiolato(1,10-pheanthrolin)nickel(II) 
• 1342805-67-7 Ni(C₆H₅CSC₆H₅CS)2(C₇H₇OCOCH₃) 
• 134-81-6 benzil 
• 42574-02-7 4,5-diphenyl-1,3-dithio-4-cyclopenten-2-one 
• 119490-45-8 4,5-Bis(benzoylseleno)-1,3-dithiole-2-thione 
• 68494-08-6 4,5-bis(benzoylthio)-1,3-dithiole-2-thione 
• 29477-12-1 C₃₅H₂₈NiS₄ 

Downstream Products

• 115261-72-8 2-[2-(5,6-Diphenyl-[1,4]dithiin-2-yl)-ethoxy]-tetrahydro-pyran 
• 115261-70-6 Acetic acid 5,6-diphenyl-[1,4]dithiin-2-ylmethyl ester 
• 115261-74-0 2-Butyl-3-((E)-3,7-dimethyl-octa-2,6-dienyl)-5,6-diphenyl-[1,4]dithiine 
• 115261-73-9 5-(2-Benzyloxy-ethyl)-2,3-diphenyl-[1,4]dithiine 
• 108175-91-3 4,5-diphenyl-3,6-dithiatricyclo-<6.2.1.0^2,7>-undeca-4,9-diene 
• 7664-93-9 sulfuric acid 
• 501-65-5 diphenyl acetylene 
• 14434-55-0 (C₃₅H₂₈S₄)Ni 
• 29477-12-1 C₃₅H₂₈NiS₄ 
• 153148-06-2 {Ni(1,2-diphenylethene-1,2-dithiolato^(2-)-S,S')(phenylenebis(methylphenylphosphine))} 
• 153148-08-4 {Ni(1,2-diphenylethene-1,2-dithiolato^(2-)-S,S')(C₆H₄(PMe₂)(PPh₂)-1,2)} 
• 153148-05-1 {Ni(1,2-diphenylethene-1,2-dithiolato^(2-)-S,S')(C₆H₄(PMePh)(PPh₂)-1,2)} 
• 74542-95-3 (SC(C₆H₅)C(C₆H₅)S)2Ni^(1-)*(CH₃)4N⁽¹⁺⁾ = [(SC(C₆H₅)C(C₆H₅)S)2Ni](CH₃)4N 
• 12123-74-9 W(CO)2(S₂C₂(C₆H₅)2)2 

Relevant articles and documents

Photooxidation of Bisnickel(O)-tetrabutylamine with α-Tocopherol

The photooxidation of a nickel dithiolate complex by α-tocopherol was found for the development of a recording medium which can be used to read by a laser diode.The mechanism was analyzed.As a result, it was found that α-tocopherol produced oxygen adducts

Heteroleptic bis(cis -1,2-disubstituted ethylene-1,2-dithiolato)nickel complexes obtained by ligand-exchange reaction: Synthesis and properties

The ligand-exchange reaction has been investigated to synthesize nickel bis(dithiolene) complexes bearing one hydroxyl functional group aimed at being grafted thereafter onto polymer materials. This reaction leads easily to heteroleptic complexes with the ethylene-1,2-dithiolato core substituted by either alkyl or aryl moieties. Details on synthetic parameters are given. A direct link between the electronic properties of the obtained molecules and those of the parent complexes involved in the ligand-exchange reaction is highlighted and also demonstrates that this reaction is a powerful method for preparing nickel complexes with tailor-made frontier orbital energies.

A bioorthogonal quadricyclane ligation

New additions to the bioorthogonal chemistry compendium can advance biological research by enabling multiplexed analysis of biomolecules in complex systems. Here we introduce the quadricyclane ligation, a new bioorthogonal reaction between the highly strained hydrocarbon quadricyclane and Ni bis(dithiolene) reagents. This reaction has a second-order rate constant of 0.25 M-1 s-1, on par with fast bioorthogonal reactions of azides, and proceeds readily in aqueous environments. Ni bis(dithiolene) probes selectively labeled quadricyclane-modified bovine serum albumin, even in the presence of cell lysate. We have demonstrated that the quadricyclane ligation is compatible with, and orthogonal to, strain-promoted azide-alkyne cycloaddition and oxime ligation chemistries by performing all three reactions in one pot on differentially functionalized protein substrates. The quadricyclane ligation joins a small but growing list of tools for the selective covalent modification of biomolecules.