Journal of the Chemical Society. Perkin transactions II p. 1995 - 1998 (1988)
Update date:2022-08-17
Topics:
Monzo, Isidro S.
Palou, Juan
Roca, Jose
Valero, Rosa
Interaction between chloranil (CA) and n-butylamine (A) at several temperatures has been studied by u.v.-visible spectroscopy.Kinetic and thermodynamic parameters, as well as a mechanism, have been proposed for this reaction.The results indicate the initial formation of charge-transfer complexes between CA and A, in the presence of an excess of amine, which decomposes to give a final product (D) (disubstituted product of CA).The reaction path is autocatalysed by the presence of amine.
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