28987-86-2

Basic information

• Product Name: ((1E,3Z)-4-Nitro-penta-1,3-dienyl)-benzene
• CAS NO: 28987-86-2
• Molecular Weight: 189.214
• Mol File: 28987-86-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: ((1E,3Z)-4-Nitro-penta-1,3-dienyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: ((1E,3Z)-4-Nitro-penta-1,3-dienyl)-benzene(28987-86-2)
• EPA Substance Registry System: ((1E,3Z)-4-Nitro-penta-1,3-dienyl)-benzene(28987-86-2)

Safety Data

• Hazardous Substances Data: 28987-86-2(Hazardous Substances Data)

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 79-24-3 Nitroethane 
• 104-55-2 3-phenyl-propenal 
• 60593-26-2 (1-nitroethyl)-phosphonic acid diethyl ester 

Downstream Products

• 3042-21-5 2-methyl-5-phenyl-1H-pyrrole 
• 1397266-43-1 (E,3S,4R)-4-nitro-1-phenylpent-1-en-3-yl ethanethioate 
• 1402405-59-7 (E)-1,2,3,4,5-pentafluoro-6-(1-nitro-4-phenylbut-3-en-2-yl)benzene 
• 877-94-1 phenyl-5 pentene-4 one-2 
• 10521-97-8 5-phenyl-pent-3-en-2-one 

Relevant articles and documents

Substituted pyrrole synthesis from nitrodienes

Though the Cadogan-Sundberg approach has been employed to synthesize a variety of indole and carbazole derivatives from nitroarenes, surprisingly, very little is reported for making pyrroles using the same approach from non-arene nitrodienes. Herein, we report a general method to synthesize substituted pyrroles, in one step with modest yields, from nitrodienes using triphenylphosphine in the presence of an Mo catalyst, bis(acetylaceto)dioxomolybdenum (VI). To shed light on the mechanism of this reaction, we performed DFT calculations using uB3LYP/6-31+G(d) basis set and observed that the reaction favors a path through a nitrene intermediate.

A Simple Unusual One-Step Conversion of Aromatic Aldehydes into Nitriles

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