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28995-75-7

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28995-75-7 Usage

Description

(1E)-2-iodohex-1-en-1-yl 4-methylphenyl sulfone is a unique sulfone compound characterized by the presence of an iodine atom and a double bond within its structure. This organic chemical, also referred to as 2-iodohex-1-enyl 4-methylphenyl sulfone, is utilized in the realm of organic chemistry and serves as a key component in the synthesis of a variety of organic compounds.

Uses

Used in Organic Chemistry:
(1E)-2-iodohex-1-en-1-yl 4-methylphenyl sulfone is employed as a synthetic intermediate for the creation of complex organic molecules, capitalizing on its distinctive structural features, including the iodine atom and the double bond.
Used in Pharmaceutical Industry:
In the pharmaceutical sector, (1E)-2-iodohex-1-en-1-yl 4-methylphenyl sulfone is used as a building block for the development of novel pharmaceutical compounds. Its unique properties and reactivity contribute to the design and synthesis of potential drug candidates.
Used in Biotechnology:
(1E)-2-iodohex-1-en-1-yl 4-methylphenyl sulfone also finds application in biotechnology, where it may be utilized in the synthesis of bioactive molecules or as a component in the development of new biotechnological processes.
Used in Material Science:
Within the field of material science, (1E)-2-iodohex-1-en-1-yl 4-methylphenyl sulfone is used as a component in the synthesis of advanced materials, potentially contributing to the creation of new materials with specialized properties.
Further research and studies are essential to fully explore the potential applications and benefits of (1E)-2-iodohex-1-en-1-yl 4-methylphenyl sulfone across various industries, given its unique structural attributes and reactivity.

Check Digit Verification of cas no

The CAS Registry Mumber 28995-75-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,8,9,9 and 5 respectively; the second part has 2 digits, 7 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 28995-75:
(7*2)+(6*8)+(5*9)+(4*9)+(3*5)+(2*7)+(1*5)=177
177 % 10 = 7
So 28995-75-7 is a valid CAS Registry Number.

28995-75-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-[(E)-2-iodohex-1-enyl]sulfonyl-4-methylbenzene

1.2 Other means of identification

Product number -
Other names (E)-2-iodo-1-tosyl-1-hexene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:28995-75-7 SDS

28995-75-7Relevant articles and documents

Solvent-Driven Mono- and Bis-sulfenylation of (E)-β-Iodovinyl Sulfones with Thiols for Flexible Synthesis of 1,2-Thiosulfonylalkenes and 1,2-Dithioalkenes

Krishna, Gamidi Rama,Kumari, Arram Haritha,Reddy, Raju Jannapu,Sharadha, Nunavath

supporting information, (2022/03/16)

The nature of solvent is a key factor for stereoselective mono- and bis-thiolation of (E)-β-iodovinyl sulfones with thiols under basic conditions. A novel and unprecedented vicinal bisthiolation of (E)-β-iodovinyl sulfones with thiols under the influence of K2CO3/DMSO at room temperature for quick assembly of (E)-1,2-dithio-1-alkenes is presented. Solvent-induced stereoselective monosulfenylation of (E)-β-iodovinyl sulfones with thiols has also been established for the synthesis of both (E)- and (Z)-1,2-thiosulfonylethenes in MeCN and MeOH, respectively. Moreover, K2CO3-mediated desulfonylative-sulfenylation of (Z)-1,2-thiosulfonylethenes with thiols in DMSO furnished unsymmetrical (Z)-1,2-dithio-1-alkenes for the first time. The solvent-dependent versatile reactivity of (E)-β-iodovinyl sulfones has been successfully explored to provide a set of (E)-/(Z)-1,2-dithio-1-alkenes and (E)-/(Z)-1,2-thiosulfonyl-1-alkenes in good to high yields with excellent stereoselectivities. Notably, this operationally simple process utilizes a broad substrate scope with good functional group tolerance and compatibility. The efficacy of the process has been proven for gram-scale reactions, and plausible mechanistic models are outlined on the basis of experimental results and control experiments.

Electrochemical Induced Regio- and Stereoselective Difunctionalization of Alkynes: The Synthesis of (E)-β-Iodovinyl Sulfones

Zhang, Xinghua,Lu, Danna,Wang, Zhenwei

supporting information, p. 4284 - 4287 (2021/06/16)

An efficient, green, and oxidant-free electrochemical method for alkyne difunctionalization was described. Using undivided electrochemical cell for iodosulfonylation of alkynes with commercially available iodide radical (NaI), arylsulfonyl radical (ArSOs

Unprecedented Reactivity of β-Iodovinyl Sulfones: An Efficient Synthesis of β-Keto Sulfones and β-Keto Thiosulfones

Reddy, Raju Jannapu,Kumar, Jangam Jagadesh,Kumari, Arram Haritha

supporting information, p. 3771 - 3775 (2019/06/24)

An unprecedented reactivity of (E)-β-iodovinyl sulfones in the presence of NaOAc is reported. The (E)-β-iodovinyl sulfones were treated with NaOAc in DMSO/H2O to yield β-keto sulfones in moderate to high yields. A novel oxidative difunctionalization of β-iodovinyl sulfones with thiosulfonates and NaOAc in DMF has been developed. This metal-free oxosulfenylation is an operationally simple to access a wide range of β-keto thiosulfones (α-thioaryl-β-keto sulfones) in moderate to high yields. The transformations were reliable at gram-scale, thus illustrating its efficiency and practicality. A plausible mechanism for the protocol is also proposed.

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