105235-57-2

Basic information

• Product Name: Benzene, 1-(1-hexenylsulfonyl)-4-methyl-, (Z)-
• CAS NO: 105235-57-2
• Molecular Formula: C13H18O2S
• Molecular Weight: 238.351
• Mol File: 105235-57-2.mol

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(1-hexenylsulfonyl)-4-methyl-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1-hexenylsulfonyl)-4-methyl-, (Z)-(105235-57-2)
• EPA Substance Registry System: Benzene, 1-(1-hexenylsulfonyl)-4-methyl-, (Z)-(105235-57-2)

Safety Data

• Hazardous Substances Data: 105235-57-2(Hazardous Substances Data)

Upstream product

• 108895-67-6 1-(p-tolylsulfonyl)-1-hexyne 
• 693-02-7 hex-1-yne 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 7257-26-3 sodium p-toluenesulfinate tetrahydrate 
• 592-41-6 1-hexene 
• 71963-96-7 2-iodo-1-tosylhexane 
• 28995-75-7 (E)-1-((2-iodohex-1-en-1-yl)sulfonyl)-4-methylbenzene 
• 106-45-6 para-thiocresol 

Downstream Products

• 90633-60-6 1-[((E)-Hex-2-ene)-1-sulfonyl]-4-methyl-benzene 
• 1380035-53-9 C₂₀H₂₆O₂S 
• 105465-49-4 1-{1-[1-(Toluene-4-sulfonyl)-ethyl]-pentyl}-pyrrolidine 
• 105465-59-6 1-[((E)-Hept-2-ene)-2-sulfonyl]-4-methyl-benzene 
• 105235-59-4 (Z)-2-hexenyl p-tolyl sulfone 
• 105235-55-0 (E)-1-(hex-2-en-1-ylsulfonyl)-4-methylbenzene 
• 105465-39-2 2-(1-pyrrolidinyl)-1-tosylhexane 

Relevant articles and documents

The synthesis of ethenyl bifunctional reagents containing a sulfone moiety and zirconium by the abnormal addition of Cp2Zr(H)Cl to internal acetylenic sulfones

Ethenyl bifunctional reagents containing a sulfone moiety and zirconium are prepared by the abnormal addition of Cp2Zr(H)Cl to internal acetylenic sulfones.

Reactions of (E)-2-Iodo-1-tosyl-1-alkenes as Useful Synthetic Intermediates

(E)-2-Iodo-1-tosyl-1-alkenes readily available by iodosulfonization of 1-alkynes were found to be useful synthons for the regio- and/or stereoselective preparation of 1-tosyl-1-alkynes, 1-tosyl-2-alkynes, (Z)-vinyl and (Z)-allyl sulfones, β-tosyl enamines

Regio- and Stereoselective Synthesis of (E)- and (Z)-Vinylic Sulfones and Their Conversion to the Corresponding Allylic Sulfones

(E)- and (Z)-vinilyc sulfones were prepared regio- and stereoselectively from 1-alkenes or 1-alkynes in high yields via iodosulfonization in AcOEt-H2O.The vinylic sulfones thus prepared were converted to the corresponding allylic sulfones by treatment wit

CONVENIENT METHODS FOR THE PREPARATION OF VINYLIC AND ALLYLIC SULFONES FROM ALKENES

1 or 2-p-Toluenesulfonyl(=tosyl)-1-alkenes were regioselectively prepared from 1-alkenes via iodosulfonization or sulfonylmercuration, respectively.Conversion of 1-tosyl-1-alkenes to the corresponding allylic sulfones, 1-tosyl-2-alkenes, was achieved by t