29091-98-3

Upstream product

• 7553-56-2 iodine 
• 54733-53-8 [Ru(N₂C₆H₄F-p)(CO)2(PPh₃)2]BF₄ 
• 144-55-8 sodium hydrogencarbonate 
• 13755-29-8 sodium tetrafluoroborate 
• 603-35-0 triphenylphosphine 
• 29145-91-3 {RuI₂(CO)2(py)2} 

Relevant academic research and scientific papers

On the reactivity of tris(triphenylphosphine)triruthenium enneacarbonyl

By reaction of [Ru(CO)3P(C6H5)3]3 with CO, Ru(CO)4P(C6H5)3 has been prepared from which, with halogens (X = Cl, Br, I) or CHCl3, [RuX2(CO)2P(C6H5)3] 2 complexes were obtained. These last compounds could also be formed from [Ru(CO)3P-(C6H5)3]3 and halogens. From the ir spectral data a structure with bridging halogens is suggested for the dimeric compounds [RuX2(CO)2P(C6H5)3] 2. [Os(CO)3P(C6H5)3]3 reacts with CO with displacement of P(C6H5)3 and formation of [Os(CO)4]3.