292048-32-9Relevant academic research and scientific papers
A novel carbocationic species paired with tetrakis(pentafluorophenyl)borate anion in catalytic aldol reaction
Mukaiyama, Teruaki,Yanagisawa, Manabu,Iida, Daisuke,Hachiya, Iwao
, p. 606 - 607 (2000)
The aldol reaction of several aldehydes with silyl enol ethers proceeded smoothly to give the corresponding aldols in good to high yields at -78 °C by using 1.0 mol% of a novel cationic species with tetrakis(pentafluorophenyl)borate anion.
VERSATILE RELATIVE AND ABSOLUTE STEREOCONTROL IN STANNOUS TRIFLATE MEDIATED ALDOL-TYPE REACTIONS OF 3-(2-BENZYLOXYACETYL)THIAZOLIDINE-2-THIONE
Mukaiyama, Teruaki,Iwasawa, Nobuharu
, p. 753 - 756 (2007/10/02)
In the stannous triflate mediated aldol-type reactions of 3-(2-benzyloxyacetyl)thiazolidine-2-thione, stereochemical course of the reactions is dramatically altered by the addition of tetramethylethylenediamine as a ligand.High asymmetric induction is also achieved by the addition of chiral diamine derived from L-prolin.
