2925-57-7Relevant articles and documents
Stille cross-coupling of secondary and tertiary α-(trifluoromethyl)-benzyl chlorides with allylstannanes
Punna, Nagender,Harada, Kyosuke,Shibata, Norio
supporting information, p. 7171 - 7174 (2018/07/05)
A Stille cross-coupling reaction was developed that delivers for the first time trifluoromethyl-substituted homoallyl compounds from α-(trifluoromethyl)benzyl chlorides and allylstannanes. This reaction proceeds even with low catalyst loadings (1 mol%) vi
Gas phase substituent effects. Stabilities of 1-aryl-2,2,2-trifluoroethyl cations
Hishima, Masaaki,Inoue, Hiroki,Fujio, Mizue,Tsuno, Yuho
, p. 685 - 688 (2007/10/02)
Gas-phase stabilities of 1-aryl-2,2,2-trifluoroethyl cations were determined based on chloride-transfer equilibria. The substituent effect was analyzed based on the LArSR Eq., giving a remarkably high r of 1.53 and a ρ of -14.6.