292607-11-5

Upstream product

• 286376-23-6 4-methyl-N-(prop-1-yn-1-yl)benzenesulfonamide 
• 563-47-3 3-Chloro-2-methylpropene 
• 70-55-3 toluene-4-sulfonamide 
• 286376-22-5 N-tert-butoxycarbonyl-N-(but-2-yn-1-yl)-(4-methylphenyl)sulfonamide 
• 513-42-8 3-hydroxy-2-methyl-1-propene 
• 18303-04-3 N-[(tert-butoxy)carbonyl]-4-methylbenzenesulfonamide 
• 132330-45-1 4-methyl-N-(2-methylallyl)-N-(prop-2-ynyl)benzenesulfonamide 
• 74-88-4 methyl iodide 
• 55022-46-3 4-methyl-N-prop-2-ynylbenzenesulfonamide 
• 1458-98-6 2-methyl-3-bromo-1-propene 
• 98-59-9 p-toluenesulfonyl chloride 
• 1206-41-3 N-(2-methylallyl)-4-toluenesulfonamide 
• 3355-28-0 1-Bromo-2-butyne 

Downstream Products

• 1361181-70-5 1,6-dimethyl-3-(p-nitrophenysulfonyl)-3-azabicyclo[4.1.0]-hept-4-ene 
• 1221596-42-4 1,6-dimethyl-3-(p-nitrophenysulfonyl)-3-azabicyclo[4.1.0]-hept-4-ene 
• 1260522-62-0 N-(but-2-ynyl)-4-methyl-N-((2-methyloxiran-2-yl)methyl)benzenesulfonamide 

Relevant academic research and scientific papers

Synthesis of Chlorotrifluoromethylated Pyrrolidines by Electrocatalytic Radical Ene-Yne Cyclization

The stereoselective synthesis of chlorotrifluoromethylated pyrrolidines was achieved using anodically coupled electrolysis, an electrochemical process that combines two parallel oxidative events in a convergent and productive manner. The bench-stable and

Palladium-catalyzed oxidative 6-exo-trig cyclization of 1,6-enynes: Facile synthesis of bicyclo[4.1.0]heptan-5-ones

We here describe a new palladium-catalyzed oxidative 6-exo-trig cyclization of 1,6-enynes at room temperature using tBuONO as an oxidant for the synthesis of 3-bicyclo[4.1.0]heptan-5-ones. This cascade strategy involves the hydration, cyclization and cycl

Cyclometalated N-heterocyclic carbene-platinum catalysts for the enantioselective cycloisomerization of nitrogen-tethered 1,6-enynes

Platinum(II) complexes which combine six-membered N-heterocyclic carbene-containing metallacyclic units and monodentate chiral phosphines have been prepared. The key step of their synthesis is the intramolecular oxidative addition of N-2-iodobenzylimidazo

Enantioselective IrI-catalyzed carbocyclization of 1,6-enynes by the chiral counterion strategy

Enantioenriched bicyclo[4.1.0]hept-2-enes were synthesized by Ir I-catalyzed carbocyclization of 1,6-enynes. No chiral ligands were used, CO and PPh3 were the only ligands bound to iridium. Instead, the stereochemical information was

(Pentamethylcyclopentadienyl)iridium dichloride dimer {[IrCp*Cl 2]2}: A novel efficient catalyst for the cycloisomerizations of homopropargylic diols and N-tethered enynes

(Pentamethylcyclopentadienyl)iridium dichloride dimer {[IrCp*Cl 2]2}-catalyzed hydroalkoxylation of bis-homopropargylic alcohols provides an efficient access to dioxabicyclo[2.2.1]ketals. The cycloisomerizations proceed under mild conditions, with low catalytic loadings and short reaction times. This new protocol involving an Ir(III) catalyst also promoted the cycloisomerization of nitrogen-tethered 1,6-enynes to give azabicyclo[4.1.0]heptenes, enhancing the synthetic potential of our method. Copyright

Radical cyclizations terminated by Ir-Catalyzed hydrogen atom transfer

A system for coupling catalytic radical cyclization and Ir-catalyzed hydrogen atom transfer (HAT) is described. It is essential that the HAT catalyst activates H2 quickly and is not a hydrogenation catalyst. Vaska's complex was found to fulfill both purpo

Enantioselective construction of quaternary carbon centers by catalytic [2 + 2 + 2] cycloaddition of 1,6-enynes and alkynes

(Chemical Equation Presented) The enantioselective [2 + 2 + 2] cycloaddition of 1,6-enynes and alkynes using chiral rhodium catalysts gave cycloadducts containing quaternary carbon stereocenters. Both symmetrical and unsymmetrical alkynes and acetylene co

Effects of substituents on the multiple bonds on ring-closing metathesis of enynes

In ring-closing metathesis (RCM) reactions of enynes, the substituents on the multiple bonds are quite important. Although RCM of an enyne having a monosubstituted alkene proceeds smoothly using the first-generation ruthenium-carbene complex 1a, that of a