29265-84-7

Basic information

• Product Name: Benzene, 1-nitro-3-(1-phenylethenyl)-
• CAS NO: 29265-84-7
• Molecular Formula: C14H11NO2
• Molecular Weight: 225.247
• Mol File: 29265-84-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, 1-nitro-3-(1-phenylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-nitro-3-(1-phenylethenyl)-(29265-84-7)
• EPA Substance Registry System: Benzene, 1-nitro-3-(1-phenylethenyl)-(29265-84-7)

Safety Data

• Hazardous Substances Data: 29265-84-7(Hazardous Substances Data)

Upstream product

• 555-68-0 m-Nitrocinnamic Acid 
• 71-43-2 benzene 
• 645-00-1 m-iodonitrobenzene 
• 4545-21-5 acetophenone p-toluenesulfonylhydrazone 
• 2206-94-2 1-acetoxy-1-phenylethene 
• 220210-17-3 tris(3-nitrophenyl)-1,3,5,2,4,6-trioxatriborinane 
• 7693-46-1 4-Nitrophenyl chloroformate 
• 100-42-5 styrene 
• 20618-66-0 m-Nitrobenzoesaeure-isopropenylester 
• 98-81-7 1-bromovinylbenzene 
• 13331-27-6 m-nitrobenzene boronic acid 
• 23171-00-8 3-Nitrobenzoesaeure-4-nitrophenylester 

Relevant articles and documents

Traceless directing group mediated branched selective alkenylation of unbiased arenes

Owing to the synthetic importance of branched olefinated products, we report palladium catalyzed formation of branched olefins facilitated by a C-H activation based protocol. This involves selective insertion of olefins and subsequent decarboxylation using a completely unbiased benzene ring as the starting precursor. The significance of the protocol has been further highlighted by exhibition of functionality tolerance along with a late-stage modification of the branched olefinated products leading to the formation of other functionalized molecules.

Construction of polysubstituted olefins through Ni-Catalyzed direct activation of Alkenyl C-O of substituted alkenyl acetates

(Figure Presented) Reliable companion: For the first time cross-coupling between alkenyl acetates and arylboroxines/PhZnCl has been developed via Ni catalysis. Alkenyl acetates could be well-differ-entiated from aryl acetates (see scheme). This reliable method provides a convenient pathway to construct polysubstituted styrene derivatives.

Synthesis of polysubstituted alkenes by Heck vinylation or Suzuki cross-coupling reactions in the presence of a tetraphosphane-palladium catalyst

Through the use of [PdCl(C3H5)]2/cis,cis,cis-1,2,3, 4-tetrakis[(diphenylphosphanyl)methyl]cyclopentane as a catalyst, a range of vinyl bromides undergo Suzuki cross-couplings with arylboronic acids in good yields. Furthermore, the catalyst can be used at low loadings, even for reactions of sterically hindered substrates. Mediated by this catalyst, stilbene and 1,1-diphenylethylene undergo Heck reactions with aryl halides to give triarylethylene derivatives. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.