293329-47-2Relevant academic research and scientific papers
Generation and reactivity of α-phosphorylated sulfur stabilised carbanions and ylides ; selective syntheses of α-thiosubstituted phosphonates
Gulea, Mihaela,Marchand, Patrice,Saquet, Monique,Masson, Serge,Collignon, Noel
, p. 327 - 328 (1999)
An asymmetric synthesis of an α-mercapto-but-3-enyl phosphonate and the preparation of various α-phosphorylated unsaturated sulfides were respectively achieved via carbanion and ylide [2,3]-sigmatropic rearrangements.
The first asymmetric synthesis of alpha-sulfanylphosphonates.
Marchand,Gulea,Masson,Saquet,Collignon
, p. 3757 - 3759 (2007/10/03)
[reaction: see text] Diastereoselectivity of up to 88% was achieved for the synthesis of an alpha-mercapto gamma-unsaturated phosphonate using the readily available chiral dimenthylphosphonyl ester group and a carbanionic [2,3]-sigmatropic rearrangement.
