Generation and reactivity of α-phosphorylated sulfur stabilised carbanions and ylides ; selective syntheses of α-thiosubstituted phosphonates

Article abstract of DOI:10.1080/10426509908546454

An asymmetric synthesis of an α-mercapto-but-3-enyl phosphonate and the preparation of various α-phosphorylated unsaturated sulfides were respectively achieved via carbanion and ylide [2,3]-sigmatropic rearrangements.

Full text of DOI:10.1080/10426509908546454

This article was downloaded by: [Princeton University]
On: 07 October 2013, At: 02:47
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number:
1072954 Registered office: Mortimer House, 37-41 Mortimer Street,
London W1T 3JH, UK
Phosphorus, Sulfur, and
Silicon and the Related
Elements
Publication details, including instructions
for authors and subscription information:
http://www.tandfonline.com/loi/gpss20
Generation and Reactivity
of α-Phosphorylated
Sulfur Stabilised
Carbanions and Ylides;
Selective Syntheses
of α-Thiosubstituted
Phosphonates
Mihaela Gulea , Patrice Marchand , Monique
Saquet , Serge Masson & Noël Collignon
a Laboratoire de Chimie Moléculaire et
Thio-organique, UMR CNRS 6507, ISMRA-
Université de Caen, 14050 Caen
b Laboratoire de Chimie Moléculaire et
Thio-organique, UMR CNRS 6507, ISMRA-
Université de Caen, 14050 Caen
c Laboratoire de Chimie Moléculaire et
Thio-organique, UMR CNRS 6507, ISMRA-
Université de Caen, 14050 Caen
d Laboratoire de Chimie Moléculaire et
Thio-organique, UMR CNRS 6507, ISMRA-
Université de Caen, 14050 Caen
e Laboratoire de Chimie Moléculaire et
Thio-organique, UMR CNRS 6507, ISMRA-
Université de Caen, 14050 Caen

Published online: 17 Mar 2008.
To cite this article: Mihaela Gulea , Patrice Marchand , Monique Saquet ,
Serge Masson & Noël Collignon (1999) Generation and Reactivity of α-
Phosphorylated Sulfur Stabilised Carbanions and Ylides; Selective Syntheses
of α-Thiosubstituted Phosphonates, Phosphorus, Sulfur, and Silicon and the
Related Elements, 153:1, 327-328, DOI: 10.1080/10426509908546454
To link to this article: http://dx.doi.org/10.1080/10426509908546454
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of
all the information (the “Content”) contained in the publications
on our platform. However, Taylor & Francis, our agents, and our
licensors make no representations or warranties whatsoever as to
the accuracy, completeness, or suitability for any purpose of the
Content. Any opinions and views expressed in this publication are
the opinions and views of the authors, and are not the views of or
endorsed by Taylor & Francis. The accuracy of the Content should
not be relied upon and should be independently verified with primary
sources of information. Taylor and Francis shall not be liable for any
losses, actions, claims, proceedings, demands, costs, expenses,
damages, and other liabilities whatsoever or howsoever caused
arising directly or indirectly in connection with, in relation to or
arising out of the use of the Content.
This article may be used for research, teaching, and private study
purposes. Any substantial or systematic reproduction, redistribution,
reselling, loan, sub-licensing, systematic supply, or distribution in
any form to anyone is expressly forbidden. Terms & Conditions of
access and use can be found at http://www.tandfonline.com/page/
terms-and-conditions