294634-40-5Relevant articles and documents
Total Synthesis of (-)-Xishacorene B from (R)-Carvone Using a C-C Activation Strategy
Kerschgens, Isabel,Rovira, Alexander R.,Sarpong, Richmond
, p. 9810 - 9813 (2018)
The activation of C-C bonds that are traditionally viewed as unreactive, when coupled with other bond-forming processes, can offer new approaches to the synthesis of complex molecular scaffolds. In this Communication, we demonstrate the conversion of carv
Hydrotalcite catalysis for the synthesis of new chiral building blocks
Rodilla, Jesus M.,Neves, Patricia P.,Pombal, Sofia,Rives, Vicente,Trujillano, Raquel,Díez, David
, p. 834 - 840 (2016/03/19)
The use of hydrotalcites for the synthesis of two chiral building blocks in a simple way is described as a new and green methodology. The synthesis of these compounds implies a regioselective Baeyer-Villiger reaction in a very selective way with ulterior
Non-heme iron catalysis in CC, C-H, and CH2 oxidation reactions. Oxidative transformations on terpenoids catalyzed by Fe(bpmen)(OTf)2
Clemente-Tejeda, David,López-Moreno, Alejandro,Bermejo, Francisco A.
, p. 2977 - 2986 (2013/03/29)
The oxidation of terpene olefins with hydrogen peroxide in the presence of the non-hemo catalyst 5a afforded mixtures of epoxides whose composition was dependent upon the oxidation protocol used in each case. With terpenoid enones, the mixtures obtained evolved from clean epoxidation of α-ionone 23 to the clean allylic oxidation of damascone 28 due to the progressive deactivation of the electron density on the double bonds present in this series. The oxidation of bicyclic and tricyclic terpenoids afforded oxidation products coming from epoxidation, to olefin degradation, methyne and methylene activation products. Probably, the most attractive result was the synthesis of the Magnus lactone 46, from the tricyclic ether 45, with 88% yield and 100% conversion.
