29476-15-1Relevant academic research and scientific papers
Process for the ring chlorination of aromatic hydrocarbons
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, (2008/06/13)
Aromatic hydrocarbons which are monosubstituted by straight-chain or branched C1 -C12 -alkyl or by C3 -C8 -cycloalkyl can be chlorinated in the presence of Friedel-Crafts Catalysts in liquid phase on the aromatic ring if cyclic benzo-fused imines or benzo[f]-1,4-thiazepines are used as co-catalysts. This makes it possible to obtain a higher proportion of p-isomers.
Studies on the chemistry of O,N- and S,N-containing heterocycles. 3 [1]. Synthesis of 1,5-benzothiazepines with potential CNS activity
Bartsch,Erker
, p. 1151 - 1154 (2007/10/02)
The synthesis of a series of novel triazolo[3,4-d][1,5]benzothiazepines 6 and 7, obtained from the activated 1,5-benzothiazepine derivatives 3 and carbohydrazides 4,is described. Under mild reaction conditions some intermediates 5 can be isolated.
