294847-71-5Relevant academic research and scientific papers
Efficient preparation of enantiomerically pure (E)-γ-hydroxy-α,β- unsaturated p-tolylsulfoxides using lipase-mediated acylations
Guerrero De La Rosa, Victor,Ordonez, Mario,Llera, Jose Manuel
, p. 2991 - 3001 (2000)
(E)-γ-Hydroxy-α,β-unsaturated p-tolylsulfoxides 1 have been efficiently resolved via irreversible enzymatic acylation with lipase PS (Pseudonomas cepacia) and vinyl acetate. (C) 2000 Elsevier Science Ltd.
Palladium-catalyzed allylic nucleophilic substitution reactions of (E)-γ-acetoxy-α,β-unsaturated p-tolylsulfoxides
Guerrero de la Rosa, Victor,Ordoez, Mario,Llera, Jose Manuel
, p. 1089 - 1094 (2007/10/03)
Regio- and diastereoselective nucleophilic allylic substitutions of optically pure (E)-γ-acetoxy-α,β-unsaturated p-tolylsulfoxides 2 and 3 with sodium dimethyl malonate have been carried out. The reactivity of these substrates is controlled by both the ch
