29526-97-4

Upstream product

• 67-56-1 methanol 
• 104173-46-8 C₁₁H₁₂N₂O₃ 
• 75-11-6 diiodomethane 
• 4747-13-1 α-methoxystyrene 
• 93-58-3 benzoic acid methyl ester 
• 74-95-3 1,1-dibromomethane 
• 104173-43-5 methyl (1-phenylcyclopropyl)carbamate 
• 186581-53-3 diazomethane 
• 29526-96-3 1-phenylcyclopropan-1-ol 

Downstream Products

• 100683-08-7 1-methoxy-cyclopropane-carboxylic acid 
• 29526-96-3 1-phenylcyclopropan-1-ol 

Relevant academic research and scientific papers

Cyclopropanization of Methyl Carboxylates with Tebbe-Type Reagents

The methylenation reaction of methyl azulene-2-carboxylates (cf.Schemes 1 and 2) with Tebbe's or Takai's reagent is described.When the prescribed amount of Takai's reagent is applied in a four-fold excess, the corresponding cyclopropyl methyl ethers are f

Kinetics of Cyclopropyl Radical Reactions. 2. Studies on the Inversion of Cyclopropyl and 1-Methylcyclopropyl Radicals and on the Kinetics of Some Addition and Abstraction Reactions of 1-Methylcyclopropyl and 1-Methoxycyclopropyl Radicals

Laser flash photolytic studies have shown that the 1-methylcyclopropyl radical has a reactivity similar to that of the cyclopropyl radical toward styrene, β-methylstyrene, 1,4-cyclohexadiene, CCl3Br, and n-Bu3SnH but that it is more reactive toward CCl4.Chemical trapping with CCl3Br of these two radicals stereospecifically labeled with deuterium yields rate constants for their inversion at 71 deg C of (2.1 +/- 0.8) * 1011 s-1 for c-C3H4.CH3 and ca. 1012 s-1 for c-C3H5..EPR spectra of 13C-labeled radicals confirm that they are nonplanar: a13Cα = 98 and 95.9 G for c-C3H4.CH3 and c-C3H5., respectively.The similar magnitudes of these splittings implies that there is also a similar degree of deviation from planarity.The barrier to inversion is probably ca. 3 kcal/mol for both radicals but the c-C3H5. inverts more rapidly possibly because of hydrogen tunneling. 1-Methoxycyclopropyl is less reactive toward styrene and 1,4-cyclohexadiene than the other two radicals.The EPR spectrum of this radical could not be obtained.

Deamination Reactions, 45. Decomposition of 1-Arylcyclopropanediazonium Ions

1-Arylcyclopropanediazonium ions have been generated by alkaline cleavage of the analogous nitrosocarbamates in methanol.With increasing ?-donor capacity of the aryl groups, retention of the three-membered ring was enhanced while the stereoselectivity (as probed with the aid of 2-D labels) was diminished or entirely lost (4-methoxyphenyl).Where applicable, the stereoselectivity of ring opening is inferior to that of nucleophilic displacement.The data may be interpreted in terms of competing reactions (ks, kc, kΔ) of the cyclopropanediazonium ions.