29576-70-3Relevant academic research and scientific papers
DIASTEREOSELECTIVE SYNTHESIS OF (E)-1-TRIMETHYLSILYL-3-EN-1-YNES BY PALLADIUM-CATALYZED CROSS-COUPLING REACTION BETWEEN TRIMETHYLSILYLETHYNYLZINC CHLORIDE AND STEREOISOMERIC MIXTURES OF 1-BROMO-1-ALKENES
Andreini, Bianca Patrizia,Carpita, Adriano,Rossi, Renzo
, p. 5533 - 5534 (1986)
In the stereospecific palladium-catalyzed cross-coupling reaction of trimethylsilylethynylzinc chloride, (E)-1-bromo-1-alkenes react preferentially in the presence of the corresponding (Z)-stereoisomers.
A ONE POT SYNTHESIS OF CONJUGATED DIENYNES BY PALLADIUM-MEDIATED THREE COMPONENT CROSS-COUPLING REACTION
Hatanaka, Yasuo,Matsui, Koji,Hiyama, Tamejiro
, p. 2403 - 2406 (1989)
Palladium-catalyzed one-pot sequential reaction of Me3SnCCSiMe3 first with an alkenyl iodide R1I and secondly with another alkenyl (or aryl) iodide R2I in the presence of newly added (Et2N)3S+ Me3SiF2- affords conjugated dienynes R1-CC-R2 with high stereospecificity.
