A ONE POT SYNTHESIS OF CONJUGATED DIENYNES BY PALLADIUM-MEDIATED THREE COMPONENT CROSS-COUPLING REACTION

DOI: 10.1016/S0040-4039(01)80411-1

Source and publish data:

Tetrahedron Letters p. 2403 - 2406 (1989)

Update date:2022-08-28

Topics:

Authors:

Hatanaka, Yasuo

Matsui, Koji

Hiyama, Tamejiro

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Article abstract of DOI:10.1016/S0040-4039(01)80411-1

Palladium-catalyzed one-pot sequential reaction of Me3SnC<*>CSiMe3 first with an alkenyl iodide R¹I and secondly with another alkenyl (or aryl) iodide R²I in the presence of newly added (Et2N)3S⁺ Me3SiF2^- affords conjugated dienynes R¹-C<*>C-R² with high stereospecificity.

Full text of DOI:10.1016/S0040-4039(01)80411-1

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