DIASTEREOSELECTIVE SYNTHESIS OF (E)-1-TRIMETHYLSILYL-3-EN-1-YNES BY PALLADIUM-CATALYZED CROSS-COUPLING REACTION BETWEEN TRIMETHYLSILYLETHYNYLZINC CHLORIDE AND STEREOISOMERIC MIXTURES OF 1-BROMO-1-ALKENES

DOI: 10.1016/S0040-4039(00)85259-4

Source and publish data:

Tetrahedron Letters p. 5533 - 5534 (1986)

Update date:2022-08-11

Topics:

Authors:

Andreini, Bianca Patrizia

Carpita, Adriano

Rossi, Renzo

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Article abstract of DOI:10.1016/S0040-4039(00)85259-4

In the stereospecific palladium-catalyzed cross-coupling reaction of trimethylsilylethynylzinc chloride, (E)-1-bromo-1-alkenes react preferentially in the presence of the corresponding (Z)-stereoisomers.

Full text of DOI:10.1016/S0040-4039(00)85259-4

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