29608-87-5

Usage

Heterocyclic aromatic compound

2,5-di(thiophen-2-yl)thiazolo[5,4-d]thiazole consists of a ring structure containing more than one type of atom, specifically sulfur and nitrogen, which contribute to its aromatic properties.

Contains sulfur and nitrogen atoms

The compound's ring structure includes sulfur and nitrogen atoms, which are essential for its electronic and optical properties, as well as its potential applications in various technologies.

Building block in organic electronic materials

Due to its unique structure and properties, 2,5-di(thiophen-2-yl)thiazolo[5,4-d]thiazole is commonly used as a building block in the synthesis of organic semiconductors and organic photovoltaics.

Potential applications in optoelectronic devices

The compound has been studied for its potential use in optoelectronic devices, such as solar cells and light-emitting diodes, due to its distinctive electronic and optical properties.

Promising candidate for advanced technology and material science applications

The structure and properties of 2,5-di(thiophen-2-yl)thiazolo[5,4-d]thiazole make it a promising candidate for use in cutting-edge technologies and materials, potentially leading to the development of innovative devices and systems.

InChI:InChI=1/C12H6N2S4/c1-3-7(15-5-1)9-13-11-12(17-9)14-10(18-11)8-4-2-6-16-8/h1-6H

Upstream product

• 98-03-3 thiophene-2-carbaldehyde 
• 79-40-3 dithiooxamide 

Relevant academic research and scientific papers

2,5-Di-2-thienylthiazolo[4,5-d]-thiazole

The molecules of the title compound, C12H6N2S4, lie on centres of symmetry. The thiophene and thiazole rings are almost planar and their planes make a dihedral angle of 1.68 (8)°. In the crystal structure, there is a relatively short intermolecular S...S contact distance of 3.5786 (9) A.

Spray-processable thiazolothiazole-based copolymers with altered donor groups and their electrochromic properties

Two novel thiazolo[5,4-d]thiazole containing donor-acceptor type alternating copolymers, poly[2-(5-(2-decyl-2H-benzo[d][1,2,3]triazol-4-yl) thiophen-2-yl)-5-(thiophen-2-yl)thiazolo[5,4-d]thiazole] (BTzTh) and poly[2-(5-(2-decyl-2H-benzo[d][1,2,3]triazol-4-yl)furan-2-yl)-5-(furan-2-yl) thiazolo[5,4-d]thiazole] (BTzFr) were synthesized by Stille coupling polymerization and their electrochemical and electrochromic properties were explored. Electrochemical activities of the spray-casted polymer films were determined by cyclic voltammetry. To evaluate the effect of thiophene and furan moieties on the optical properties of the copolymers, spectroelectrochemistry studies were performed. To examine the switching abilities, copolymer films were subjected to a double potential step chronoamperometry in their local maximum absorptions. Both thiazolothiazole-containing copolymers showed multichromic properties with low band-gap values 1.7 and 1.9 eV for BTzTh and BTzFr, respectively. The decent electrochromical properties together with solution processability make them important candidates for electrochromic applications. Copyright

BORON-CONTAINING COMPOUND AND APPLICATION THEREFOR

PROBLEM TO BE SOLVED: To provide a boron-containing compound exhibiting excellent mobility by preparing a structure containing 2 or more nitrogen atoms in a center part of a skeleton and further crosslinked by boron. SOLUTION: There is provided a boron-containing compound represented by the following chemical formula (1), where rings X1 and X2 may be the same or different and represent a five-membered ring which may be substituted or a condensed ring having the five-membered ring, Y1 represents a condensed heterocyclic ring having a structure containing 2 or more nitrogen atoms where an azo group, a heterocycle or 2 or more rings are ring condensed and R1 to R6 may be the same or different and represent hydrogen, a halogen or a monovalent substituent. SELECTED DRAWING: None COPYRIGHT: (C)2018,JPOandINPIT

Microwave-activated synthesis of thiazolo[5,4-d]thiazoles by a condensation/oxidation sequence

A microwave-assisted preparation of symmetrical thiazolo[5,4-d]thiazoles from the corresponding aldehydes is presented. The two-step reaction sequence comprises the condensation of aldehydes with dithiooxamide followed by oxidation/aromatization with 1,4-

Synthesis and photovoltaic properties of cyclopentadithiophene-based low-bandgap copolymers that contain electron-withdrawing thiazole derivatives

We have synthesized four types of cyclopentadithiophene (CDT)based low-bandgap copolymers, poly[{4,4-bis(2-ethylhexyl)-4H-cyclopenta[2,1 -b :3,4-b']dithiophene-2,6-diy1}-alt(2,2'-bithiazole-5,5'-diy1)] (PehCDTBT), poly[(4,4-dioctyl-4H-cyclopenta[2,1-b:3,4-b']dithiophene-2,6-diyl)-alt(2, 2'-bithiazole-5,5'-diyl)] (PocCDTBT), poly[{4,4-bis(2-ethylhexyl)-4H- cyclopenta[2,1-b:3,4-b)']dithiophene-2,6diyl}-alt-{2,5-di(thiophen-2-y1) thiazolo[5,4-d]thiazole-5,5'-diy1}] (PehCDTTZ), and poly[(4,4-dioctyl-4H- cyclopenta[2,1-b:3,4-b']dithiophene-2,6diyl)-alt-{2,5-di(thiophen-2-y1) thiazolo[5,4-d]thiazole-5,5'-diy1}] (PocCDTTZ), for use in photovoltaic applications. The intramolecular charge-transfer interaction between the electronsufficient CDT unit and electron-deficient bithiazole (BT) or thiazolothiazole (TZ) units in the polymeric backbone induced a low bandgap and broad absorption that covered 300 nm to 700800 nm. The optical bandgap was measured to be around 1.9 eV for PehCDT-BT and PocCDT-BT, and around 1.8 eV for PehCDT-TZ and PocCDT-TZ. Gel permeation chromatography showed that number-average molecular weights ranged from 8000 to 14000 g mol-1. Field-effect mobility measurements showed hole mobility of 10 6-10-4 Cm2V-1 s-1 for the copolymers. The film morphology of the bulk heteroj unction mixtures with [6,6]phenyl-C61-butyric acid methyl ester (PCBM) was also examined by atomic force microscopy before and after heat treatment. When the polymers were blended with PCBM, PehCDT-TZ exhibited the best performance with an open circuit voltage of 0.69 V, short-circuit current of 7.14 mA cm-2, and power conversion efficiency of 2.23% under air mass (AM) 1.5 global (1.5 G) illumination conditions (100 mWcm-2).

THIAZOLOTHIAZOLE DERIVATIVE

A thiazolothiazole derivative is represented by the following Formula (I). In Formula (I), each R1 independently represents a straight chain alkyl group having 3 to 20 carbon atoms, a straight chain alkoxy group having 3 to 20 carbon atoms, a branched alkyl group having 3 to 20 carbon atoms, or a branched alkoxy group having 3 to 20 carbon atoms; and each R2 independently represents a hydrogen atom, a straight chain alkyl group having 1 to 20 carbon atoms, a straight chain alkoxy group having 1 to 20 carbon atoms, a branched alkyl group having 3 to 20 carbon atoms, or a branched alkoxy group having 3 to 20 carbon atoms.

Synthesis, physical properties, and field-effect transistors of novel thiophene/thiazolothiazole co-oligomers

p-Channel OFETs using thiophene/thiazolothiazole co-oligomers as active layers have been successfully fabricated, and the field-effect mobilities for these oligomers were higher than those for thiophene/thiazole co-oligomers.