29621-55-4Relevant academic research and scientific papers
Formyloxyacetoxyphenylmethane and 1,1-diacylals as versatile O-formylating and O-acylating reagents for alcohols
Chapman, Robert S.L.,Francis, Molly,Lawrence, Ruth,Tibbetts, Joshua D.,Bull, Steven D.
, p. 6442 - 6452 (2018/10/02)
Formyloxyacetoxyphenylmethane, symmetric 1,1-diacylals and mixed 1-pivaloxy-1-acyloxy-1-phenylmethanes have been used as moisture stable O-formylating and O-acylating reagents for primary and secondary alcohols, allylic alcohols and phenols under solvent/catalyst free conditions to afford their corresponding esters in good yield.
Chemoselective removal of allylic formyloxy group using SmI2
Shibuya,Shiratsuchi
, p. 431 - 449 (2007/10/02)
A variety of allylic formates are chemoselectively transformed into th corresponding olefins in excellent yields on treatment with SmI2 in THF-HMPA-H2O (20:5:1), even though allylic acetate and allylic ether groups are present in the same molecule.
Synthese von (-)-Spathulenol
Surburg, Horst,Mondon, Albert
, p. 118 - 131 (2007/10/02)
In reference to the famous synthesis of (-)-aromadendrene, the synthesis of (-)-spathulenol (31) and (-)-7-epi-spathulenol (32) from (-)-β-pinene via (-)-perillaaldehyde and the intermediates 7, 19 and 25 is described.
