296247-94-4

Usage

Uses

Used in Polymer Production:
Carbamic acid, 1,6-hexanediylbis-, bis(9H-fluoren-9-ylmethyl) ester is used as a crosslinking agent in the polymer industry for the production of high-performance polymers. Its ability to form strong bonds with other molecules results in polymers with improved mechanical properties and chemical stability.
Used in Coatings Industry:
In the coatings industry, Carbamic acid, 1,6-hexanediylbis-, bis(9H-fluoren-9-ylmethyl) ester is utilized as a crosslinking agent to produce coatings with enhanced durability and resistance to environmental factors such as UV radiation, moisture, and chemicals. This leads to longer-lasting and more robust coatings for various applications, including automotive, aerospace, and construction.
Used in Adhesives Industry:
Carbamic acid, 1,6-hexanediylbis-, bis(9H-fluoren-9-ylmethyl) ester is employed as a crosslinking agent in the adhesives industry to create adhesives with superior bonding strength and resistance to various environmental conditions. This results in adhesives that are more reliable and durable for use in a wide range of applications, such as in the assembly of electronic devices, automotive components, and construction materials.
Overall, Carbamic acid, 1,6-hexanediylbis-, bis(9H-fluoren-9-ylmethyl) ester plays a crucial role in various industries by improving the performance and reliability of polymers, coatings, and adhesives through its crosslinking capabilities. When handled with proper safety precautions and guidelines, this chemical compound offers significant benefits in the development of high-quality materials.

Upstream product

• 24324-17-2 9-Fluorenylmethanol 
• 822-06-0 Hexamethylene diisocyanate 
• 124-09-4 1,6-Hexanediamine 
• 102774-86-7 9-fluorenylmethyl N-succinimidyl carbonate 
• 28920-43-6 (fluorenylmethoxy)carbonyl chloride 

Relevant academic research and scientific papers

Flow-mediated synthesis of Boc, Fmoc, and Dd iv monoprotected diamines

A series of monoprotected aliphatic diamines (21 examples) were synthesized via continuous flow methods. The carbamates and enamines were obtained in 45-91% yields using a 0.5 mm diameter PTFE tubular flow reactor. Using readily accessible protecting group precursors, the procedure serves as an attractive alternative to existing batch-mode synthetic routes by providing direct, multigram access to N-Boc-, N-Fmoc-, and N-Ddiv-protected compounds with productivity indexes of 1.2-3.6 g/h.

NOVEL DIURETHANE COMPOUND, PROCESS FOR PRODUCING THE SAME, AND ACRYLIC RUBBER COMPOSITION CONTAINING THE SAME

Disclosed is a diurethane compound R2(SO2)m(CH2)nOCONH-R1-NHCOO(CH2)n(SO2)R2 produced by a method allowing a diamine compound H2NR1NH2 to react with a chloroformate compound ClCOO(CH2)n(SO2)mR2 or a method allowing a diisocyanate compound OCNR1NCO to react with a hydroxyl-containing compound R2(SO2)m(CH2)nOH. The diurethane compound is compounded with multivalent amine crosslinkable group-containing acrylic rubber together with a basic vulcanization accelerator to form an acrylic rubber composition. The acrylic rubber composition including the diurethane compound as a vulcanizing agent decreases a delay in the vulcanization rate due to prevention of scorching and also allows a vulcanized article to satisfy the compression set characteristics.

Nonlinear organic reaction of 9-fluorenylmethyl carbamates as base amplifiers to proliferate aliphatic amines and their application to a novel photopolymer system

A novel concept of base proliferation for improving the photosensitivity of base-sensitive materials is described by presenting the autocatalytic transformation of 9-fluorenylmethyl carbamates to aliphatic amines. A 9-fluorenylmethyl carbamate, as a base amplifier, was subjected to a base-catalysed fragmentation reaction to liberate the corresponding amine, which can then act as a catalyst for decomposing parent molecules, leading to autocatalytic decomposition. Consequently, the amine is generated from an equimolar amount of the carbamate using a catalytic amount of the same amine. 1-(9-Fluorenylmethoxycarbonyl)piperidine and 1-(9-fluorenylmethoxycarbonyl) cyclohexylamine were suitable as base amplifiers because of their thermal stability under neutral conditions and high base-catalytic reactivity. On the basis of the results, 1,3-bis[1-(9-fluorenylmethoxycarbonyl)-4-piperidyl] propane and 1,6-bis[(9-fluorenylmethoxy)carbonylamino]hexane were designed as base amplifiers which liberate aliphatic diamines to crosslink poly(glycidyl methacrylate) photochemically in the presence of a photobase generator. Addition of the base amplifiers resulted in a marked improvement of the photosensitivity characteristics of the polymer by a factor of 16 and 50, respectively.

Applications of a nonlinear organic reaction of carbamates to proliferate aliphatic amines

Base amplifiers such as the carbamate compounds 1 generate more bases than they consume. The base-catalyzed fragmentation reaction of 1 liberates the corresponding alipatic amines which catalyze the decomposition of the carbamates (see scheme). This leads to autocatalytic, nonlinear fragmentation of 1, in a novel nonlinear organic reaction. The addition of the base amplifier to an epoxy polymer sentized with a photobase generator results in the marked improvement of sensitivity.