29627-62-1Relevant articles and documents
Absolute Helical Arrangement of Sulfonamide in the Crystal
Azumaya, Isao,Kato, Takako,Okamoto, Iwao,Yamasaki, Ryu,Tanatani, Aya,Yamaguchi, Kentaro,Kagechika, Hiroyuki,Takayanagi, Hiroaki
, p. 3939 - 3942 (2003)
(Matrix presented) 1,2-Bis(N-benzenesulfonyl-N-methylamino)benzene (2), which has no fixed asymmetric element, was crystallized from ethyl acetate as chiral crystals belonging to space group P41212 (No. 92) or P4321/
BORYLIMIDE CATALYSTS
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Paragraph 0081, (2020/06/10)
The present invention provides a borylimide catalyst and further relates to compositions comprising the borylimide catalysts and processes for the polymerisation of olefins (e.g. ethylene) using the borylimide catalysts or the compositions comprising the
Carbon–carbon bond formation via benzoyl umpolung attained by photoinduced electron-transfer with benzimidazolines
Igarashi, Tomohito,Tayama, Eiji,Iwamoto, Hajime,Hasegawa, Eietsu
supporting information, p. 6874 - 6877 (2019/04/10)
A photoreaction between benzoyl compounds, such as benzoylformate derivatives, and 2-(p-anisyl)-1,3-dimethylbenzimidazoline in the presence of allyl bromide was found to give various allylated alcohols. In the reaction of benzoylformates, α-hydroxy ester enolates, for which the negative charge occurs on the carbonyl carbon of benzoyl (umpolung reactivity), are proposed to be generated as intermediates by electron-transfer from benzimidazolines to the photoexcited benzoylformates; these species react with allyl bromide to produce α-allyl-α-hydroxy esters.