29636-84-8Relevant articles and documents
Pd-catalyzed direct arylation of electron-deficient polyfluoroarenes with aryliodine(III) diacetates
Fu, Zhengjiang,Xiong, Qiheng,Zhang, Wenbiao,Li, Zhaojie,Cai, Hu
supporting information, p. 123 - 126 (2015/02/05)
A Pd-catalyzed direct arylation of electron-deficient polyfluoroarenes with readily available aryliodine(III) diacetates was developed with moderate to good yields. The process exhibited good functional tolerance with respect to methyl, methoxy, bromo, chloro, trifluoromethyl, cyano, and aldehyde groups. Mechanistic studies revealed this coupling involved in situ generation of aryl iodide from heating-promoted decomposition of aryliodine(III) diacetate, followed by coupling with polyfluoroarenes substrates to afford the desired products.
