296759-69-8Relevant articles and documents
Synthesis of 3-benzoyl-4-styryl-2-pyrazolines and their oxidation to the corresponding pyrazoles
Pinto, Diana C. G. A.,Silva, Artur M. S.,Levai, Albert,Cavaleiro, Jose A. S.,Patonay, Tamas,Elguero, Jose
, p. 2593 - 2599 (2007/10/03)
The 3-benzoyl-4-styryl-2-pyrazolines 2a-g were prepared from the regioselective 1,3-dipolar cycloaddition reactions of (E,E)- cinnamylideneacetophenones 1a-g and diazomethane. The new compounds 3-(2- benzofuranyl)-4-styryl-2-pyrazolines (5c,d) were also obtained as by-products in some cases. The oxidation of the 3-benzoyl-4-styryl-2-pyrazolines 2a-g into 3(5)-benzoyl-4-styrylpyrazoles 3a-g is also reported. Configurational and conformational features of all compounds were established by NMR spectroscopy.