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CYCLOHEXYLDIMETHYLSILANE, with the chemical formula C8H18Si, is a colorless liquid characterized by a pungent odor. It is a versatile chemical compound that serves as a coupling agent in organic synthesis and plays a significant role in the production of silicone-based materials, organosilicon compounds, and as an intermediate in the synthesis of pharmaceuticals and agrochemicals.

29681-56-9

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29681-56-9 Usage

Uses

Used in Chemical Synthesis Industry:
CYCLOHEXYLDIMETHYLSILANE is used as a coupling agent for enhancing the reactivity and selectivity of organic synthesis processes. Its ability to form stable bonds with various organic and inorganic substrates makes it a valuable component in the synthesis of complex molecules.
Used in Silicone Material Production:
In the silicone industry, CYCLOHEXYLDIMETHYLSILANE is utilized as a key component in the production of silicone-based materials. Its compatibility with silicon and organic groups allows for the creation of materials with unique properties, such as heat resistance, flexibility, and chemical stability.
Used in Organosilicon Compound Preparation:
CYCLOHEXYLDIMETHYLSILANE serves as a reagent in the preparation of organosilicon compounds, which are essential in various applications, including coatings, adhesives, and sealants. Its presence in these compounds contributes to their performance and durability.
Used in Surface Modification and Adhesion Promotion:
As a silane coupling agent, CYCLOHEXYLDIMETHYLSILANE is employed for surface modification and adhesion promotion in various industrial applications. It helps improve the bonding between different materials, leading to enhanced product performance and longevity.
Used in Pharmaceutical and Agrochemical Synthesis:
CYCLOHEXYLDIMETHYLSILANE can be utilized as an intermediate in the synthesis of pharmaceuticals and agrochemicals. Its unique properties enable the development of new and effective compounds for medical and agricultural applications.
However, it is crucial to handle CYCLOHEXYLDIMETHYLSILANE with care due to its flammable nature and potential to cause skin and eye irritation upon contact. Proper safety measures should be taken to ensure the safe use of this chemical compound in various industries.

Check Digit Verification of cas no

The CAS Registry Mumber 29681-56-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,9,6,8 and 1 respectively; the second part has 2 digits, 5 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 29681-56:
(7*2)+(6*9)+(5*6)+(4*8)+(3*1)+(2*5)+(1*6)=149
149 % 10 = 9
So 29681-56-9 is a valid CAS Registry Number.
InChI:InChI=1/C8H18Si/c1-9(2)8-6-4-3-5-7-8/h8-9H,3-7H2,1-2H3

29681-56-9 Well-known Company Product Price

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  • Aldrich

  • (305359)  Cyclohexyldimethylsilane  98%

  • 29681-56-9

  • 305359-10G

  • 1,371.24CNY

  • Detail

29681-56-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name cyclohexyl(dimethyl)silicon

1.2 Other means of identification

Product number -
Other names Cyclohexyldimethylsilane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:29681-56-9 SDS

29681-56-9Relevant academic research and scientific papers

Metal-free hydrogen evolution cross-coupling enabled by synergistic photoredox and polarity reversal catalysis

Cao, Jilei,Lu, Kanghui,Ma, Lishuang,Yang, Xiaona,Zhou, Rong

supporting information, p. 8988 - 8994 (2021/11/23)

A synergistic combination of photoredox and polarity reversal catalysis enabled a hydrogen evolution cross-coupling of silanes with H2O, alcohols, phenols, and silanols, which afforded the corresponding silanols, monosilyl ethers, and disilyl ethers, respectively, in moderate to excellent yields. The dehydrogenative cross-coupling of Si-H and O-H proceeded smoothly with broad substrate scope and good functional group compatibility in the presence of only an organophotocatalyst 4-CzIPN and a thiol HAT catalyst, without the requirement of any metals, external oxidants and proton reductants, which is distinct from the previously reported photocatalytic hydrogen evolution cross-coupling reactions where a proton reduction cocatalyst such as a cobalt complex is generally required. Mechanistically, a silyl cation intermediate is generated to facilitate the cross-coupling reaction, which therefore represents an unprecedented approach for the generation of silyl cationviavisible-light photoredox catalysis.

Versatile method for introduction of bulky substituents to alkoxychlorosilanes

Masaoka, Shin,Banno, Tadashi,Ishikawa, Mitsuo

, p. 182 - 192 (2007/10/03)

The reactions of various alkoxytrichlorosilanes prepared in situ from tetrachlorosilane and alcohols, with Grignard reagents bearing a bulky substituent such as the isopropyl, sec-butyl, and cyclohexyl group afforded triisopropyl-, tri(sec-butyl)-, and tricyclohexylalkoxysilane in high yields. The reactions of n-butoxytrichlorosilane with these Grignard reagents produced triisopropyl-, tri(sec-butyl)-, and tricyclohexyl(n-butoxy)silane in 94%, 96%, and 92% yields, respectively. Methoxymethyldichlorosilane reacted with the same Grignard reagents to give diisopropyl-, di(sec-butyl)-, and dicyclohexylmethoxymethylsilane in 84%, 83%, and 83% yields. Treatment of methoxydimethylchlorosilane with the Grignard reagents readily afforded isopropyl-, sec-butyl-, and cyclohexylmethoxydimethylsilane in excellent yields. Similar treatment of methoxydimethylchlorosilane with tert-butylmagnesium chloride gave tert-butylmethoxydimethylsilane in 62% yield.

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