62399-01-3Relevant articles and documents
Nickel(0) catalyzed oxidation of organosilanes to disiloxanes by air as an oxidant
Lv, Haiping,Laishram, Ronibala Devi,Li, Jiayan,Shi, Guangrui,Sun, Weiqing,Xu, Jianbin,Yang, Yong,Luo, Yang,Fan, Baomin
supporting information, p. 971 - 974 (2019/03/07)
We report here an efficient non-aqueous route to symmetrical disiloxanes from their corresponding organosilanes using Ni(COD)2 with 3,4,7,8-tetramethyl-1,10-phenanthroline in air. Our methodology is very simple and high yielding. The reaction mechanism is also proposed.
Supported gold nanoparticle catalyst for the selective oxidation of silanes to silanols in water
Mitsudome, Takato,Noujima, Akifumi,Mizugaki, Tomoo,Jitsukawa, Koichiro,Kaneda, Kiyotomi
supporting information; experimental part, p. 5302 - 5304 (2010/01/31)
Hydroxyapatite-supported gold nanoparticles (AuHAP) can act as highly efficient and reusable catalysts for the oxidation of diverse silanes into silanols in water; this is the first catalytic methodology for the selective synthesis of aliphatic silanols using water under organic-solvent-free conditions.
Process of producing a silanic or siloxanic compound containing at least one cycloalkyl ring
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, (2008/06/13)
A process of producing a silanic or siloxanic compound containing at least one cycloalkyl ring by hydrogenation of a corresponding compound containing at least one aromatic ring, in solution, in the presence of a catalyst comprising palladium, supported on active carbon and at a pressure equal to or higher than 10 bar.
Process for producing a silane or siloxane compound containing a cycloalkyl ring
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, (2008/06/13)
A process for producing a silane or siloxane compound containing at least one cycloalkyl ring by hydrogenation of a corresponding derivative containing at least one aromatic ring in the presence of a Raney nickel catalyst modified with chromium.
A process for producing a silanic or siloxanic compound containing at least one cycloalkylic ring
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, (2008/06/13)
A process for producing a silanic or siloxanic compound containing at least one cycloalkylic ring by hydrogenation of a corresponding particularly defined derivative containing at least one aromatic ring in the presence of a Raney nickel catalyst modified with chromium.
A process of producing a silanic or siloxanic compound containing at least one cycloalkyl ring
-
, (2008/06/13)
A process of producing a silanic or siloxanic compound containing at least one cycloalkyl ring by the hydrogenation of a corresponding compound containing at least one aromatic ring, in the presence of a Raney nickel catalyst having a granulometry comprised essentially between 10 and 150 micrometers and a surface area of at least 80 m2/g.
Influence de la taille du cycle sur la substitution electrophile des cycloalkyltrimethylsilanes. Synthese de cycloalkyldimethylfluorosilanes
Grignon-Dubois, M.,Dunogues, J.,Calas, R.
, p. 291 - 295 (2007/10/02)
Cycloalkyltrimethylsilanes, excepting cyclopropyl-, react with electrophiles by Si - Me bond splitting.Consequently silicon can be functionalized by this route.We also propose a new synthesis of cycloalkyldimethylfluoro(or chloro-)silanes.In the case of five or six member ring derivates, the observed results are interpreted by a mechanism involving initial abstraction of hydride ion from the silicon substrate.