29706-62-5

Usage

Uses

Used in Chemical Research:
2,4,6,8-Nonatetraenal, 7-methyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (2E,4Z,6E,8E)is used as a research compound for studying its unique chemical properties and potential reactions with other substances. Its complex structure provides a platform for understanding the behavior of similar compounds in chemical reactions.
Used in Pharmaceutical Development:
In the pharmaceutical industry, 2,4,6,8-Nonatetraenal, 7-methyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (2E,4Z,6E,8E)is used as a starting material or intermediate in the synthesis of new drug molecules. Its unique structure may contribute to the development of novel therapeutic agents with specific pharmacological properties.
Used in Material Science:
2,4,6,8-Nonatetraenal, 7-methyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (2E,4Z,6E,8E)is used as a component in the development of new materials with specialized properties. Its complex structure may be utilized to create materials with unique characteristics, such as improved strength, flexibility, or chemical resistance, depending on the application.

Upstream product

• 103410-75-9 4,4-diethoxy-but-2t-enal 
• 53282-28-3 [(2E,4E)-3-methyl-5-(2,6,6-trimethylcyclohex-1-en-1-yl)penta-2,4-dienyl]triphenylphosphonium chloride 
• 29706-61-4 9-cis-13-demethyl-retinal 
• 24336-20-7 7-methyl-9-(2,6,6-trimethylcyclohex-1-enyl)nona-2,4,6,8-tetraenal 
• 59057-30-6 (1E)-1-(2,6,6-trimethylcyclohex-1-enyl)-3-methyl-1,4-pentadien-3-ol 
• 5299-98-9 (2E,4E)-3-methyl-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-dienenitrile 
• 4807-58-3 methyl 13-desmethyl-retinoate 
• 79-77-6 (E)-β-ionone 
• 4807-99-2 all-trans-13-demethylretinol 
• 62285-98-7 5-(2,6,6-trimethylcyclohexenyl)-3-methyl-2,4-pentadienyltriphenylphosphonium bromide 
• 204326-62-5 2-((1E,3E,5Z)-6-Bromo-3-methyl-hexa-1,3,5-trienyl)-1,3,3-trimethyl-cyclohexene 
• 100846-84-2 2-((1E,3E)-6,6-Dibromo-3-methyl-hexa-1,3,5-trienyl)-1,3,3-trimethyl-cyclohexene 
• 3917-41-7 (2E,4E)-3-methyl-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,4-pentadienal 
• 247168-85-0 (2E,4Z,6E,8E)-7-Methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraen-1-ol 

Downstream Products

• 24336-20-7 7-methyl-9-(2,6,6-trimethylcyclohex-1-enyl)nona-2,4,6,8-tetraenal 

Relevant academic research and scientific papers

Structural Assignment of Isomeric Chain Demethylated Retinals by (1)H NMR Spectroscopy

Geometric isomers of all-trans-9-demethyl-, -13-demethyl- and -9,13-bisdemethylretinal were prepared.The 360 MHz (1)H NMR spectra of 13 geometric isomers of these three demethylated retinal systems have been measured.The chemical shift and couplimg constant values in each case allowed an unambiguous assignment of the structure of each compound.

Contribution of methyls in retinal side chain to regioselective photoisomerization of retinochromes

All-trans-9-demethyl-11-methylretinal was synthesized to elucidate the chromophoric interaction between hydrophobic part in retinochrome and 9-methyl substituent of retinal. Photoirradiation of its pigment efficiently gave the 11-cis-isomer in 90% regiose

Retinoids and Carotenoids, V.- Synthesis of Modified Retinals

The syntheses of 13-demethyl-13-ethyl-, 13-demethyl-13-propyl-, 13-demethyl-, 13-demethyl-14-methyl-, and 14-methylretinal are described.The UV spectra of some geometric isomers of these compounds are discussed.

Preparation of 11,14-epoxy-bridged and isomeric chain-demethylated retinals. 13-Demethyl-11,14-epoxy-, 9-demethyl-, 13-demethyl- and 9,13-bisdemethyl-retinals

9-Cis- and all-trans-13-demethyl-11,14-epoxyretinyl acetate were prepared via a Wittig coupling between β-ionylidenetriphenylphosphonium bromide (1) and 5-(acetoxymethyl)furfural.Saponification of these acetates, subsequent oxidation and HPLC separation a

On the photoisomerisation of 13-desmethyl-retinal

All mono-cis-isomers of 13-desmethyl-retinal have been prepared fro the alll-trans-compound by photoisomerisation. The various isomers were separated by HPLC and identified by their 400 MHz-1NMR-spectra.

Photochemistry of Linear Polyenes Related to Vitamin A. 13-Demethylretinal and 14-Methylretinal

The photochemistry of all-trans-13-demethylretinal (2) and all-trans-14-methylretinal (3) is examined in nonpolar and polar solvents.Upon extended irradiation into the first adsorption band, a photoequilibrium mixture is established that contains a number of isomeric photoproducts.High pressure liquid chromatographic methods are employed to isolate and purify each reaction product, and their adsorption spectral and photochemical properties are examined.Primary photoproducts and quantum yields (ψPI of trans -> cis or cis -> trans photoisomerization for all-trans-, 7-cis-, 9-cis-, and 11-cis-13- demethylretinal and all-trans-, 9-cis-, 11-cis-, and 13-cis-14-methylretinal are determined in a nonpolar solvent.The variation in ψPI and the relative photoproduct ratios of the isomers of 13-demethylretinal and 14-methylretinal differ from those of the corresponding isomers of retinal.The differences in quantum yields, primary products, and their relative ratios are analyzed in terms of the structural changes resulting from incorporation or removal of the alkyl substituent of the C-13-C-14 carbon-carbon double bond.