297747-12-7Relevant academic research and scientific papers
A facile and eco-friendly method for the synthesis of 1,2-orthoesters of carbohydrates in ionic liquid
Radhakrishnan,Sajisha,Chacko, Jessy Maria
, p. 997 - 999 (2005)
A facile method for the synthesis of 1,2-orthoesters of carbohydrates in ionic liquid [bmim]PF6 is described. The method described herein is simpler, eco-friendly and avoids the addition of quaternary ammonium salts as promoters.
Impact of Aromatic Stacking on Glycoside Reactivity: Balancing CH/πand Cation/πInteractions for the Stabilization of Glycosyl-Oxocarbenium Ions
Montalvillo-Jiménez, Laura,Santana, Andrés G.,Corzana, Francisco,Jiménez-Osés, Gonzalo,Jiménez-Barbero, Jesús,Gómez, Ana M.,Asensio, Juan Luis
supporting information, p. 13372 - 13384 (2019/09/10)
Carbohydrate/aromatic stacking represents a recurring key motif for the molecular recognition of glycosides, either by protein binding domains, enzymes, or synthetic receptors. Interestingly, it has been proposed that aromatic residues might also assist i
Ionic liquid [bmim]PF6-mediated synthesis of 1,2-orthoesters of carbohydrates and the glycosidation reactions of 4-pentenyl orthoesters
Anas, Saithalavi,Sajisha, Valiyaveetil Sanjayan,Rajan, Rani,Kumaran, Rajasekaran Thirumalai,Radhakrishnan, Kokkuvayil Vasu
, p. 553 - 560 (2008/02/11)
A facile synthesis of the 1,2-orthoesters of carbohydrates in the ionic liquid [bmim]PF6 without a quaternary ammonium salt like tetrabutylammonium iodide, is described. The glycosidation reactions of 4-pentenyl orthoesters (NPOEs) with differe
