29868-41-5Relevant academic research and scientific papers
Chemoenzymatic synthesis of naturally occurring benzyl 6-O-glycosyl-β- D-glucopyranosides
Kawahara, Eiji,Fujii, Mikio,Kato, Keisuke,Ida, Yoshiteru,Akita, Hiroyuki
, p. 1058 - 1061 (2007/10/03)
Direct β-glucosidation between benzyl alcohol and D-glucose (5) using the immobilized β-glucosidase from almonds with the synthetic prepolymer ENTP-4000 gave a benzyl β-D-glucoside (1) in 53% yield. The coupling of the benzyl β-D-glucopyranoside congener
Synthesis of Ganglioside M5 from Sea Urchin Egg
Yamamoto, Toshihiro,Teshima, Tadashi,Saitoh, Umihito,Hoshi, Motonori,Shiba, Tetsuo
, p. 2701 - 2704 (2007/10/02)
A main component of ganglioside M5 from egg of the sea urchin, Anthocidaris crassispina, Neu5Gcα2->6Glcβ1->1Cer (1), which has N-glycolyl group in neuraminic acid part, as well as phytosphingosine and saturated nonhydroxy fatty acid in ceramide part was f
Syntheses of Benzyl 6-O-Sulfo-β-D-glucopyranoside Salts and Their 6S-Deuterated Analogues. Conformational Preferences of Their (Sulfonyloxy)methyl Group
Meyer, Bernd,Stuike-Prill, Rainer
, p. 902 - 906 (2007/10/02)
The syntheses of benzyl 6-O-sulfo-β-D-glucopyranoside as the sodium (7), lithium (8), potassium (9), and calcium (10) salts in 30percent total yield from D-glucose are described.Sulfation of the 6-hydroxy compounds 5 and 17 involved quenching of the react
A New Method for Cleaving Carbohydrate Triphenylmethyl and Benzyl Ethers
Klemer, Almuth,Bieber, Michael,Wilbers, Hubert
, p. 1416 - 1421 (2007/10/02)
Carbohydrate triphenylmethyl and benzyl ethers are converted into their trimethylsilyl ethers by iodotrimethylsilane.The silyl ethers are hydrolysed to give partially free sugars.From multiple benzylated glycosides it is possible to remove selectively the primary benzyl group, under more vigorous conditions total debenzylation occurs.
