298713-13-0

Upstream product

• 1193-82-4 racemic methyl phenyl sulfoxide 
• 298713-12-9 2,2-dimethyl propionic acid (3S,10S,6E)-10-formyl-3,7,11-trimethyl-dodec-6-enyl ester 
• 298713-09-4 2,2-Dimethyl-propionic acid (E)-(S)-10-hydroxymethyl-3,7,11-trimethyl-dodeca-6,10-dienyl ester 
• 298713-07-2 2,2-Dimethyl-propionic acid (E)-(S)-10-hydroxymethyl-3,7,11-trimethyl-dodeca-6,11-dienyl ester 
• 298713-08-3 2,2-Dimethyl-propionic acid (E)-(S)-10-formyl-3,7,11-trimethyl-dodeca-6,10-dienyl ester 
• 298713-06-1 2,2-Dimethyl-propionic acid (E)-(S)-3,7,11-trimethyl-dodeca-6,10-dienyl ester 
• 20576-54-9 (3S)-(6E)-2,3-dihydrofarnesol 
• 106-28-5 Farnesol 
• 646519-61-1 2,2-dimethyl propionic acid (3S,10S,6E)-9-benzenesulfonyl-10-methoxymethoxymethyl-3,7,11-trimethyl-dodec-6-enyl ester 
• 646519-62-2 2,2-dimethyl propionic acid (3S,10S,6E)-10-methoxymethoxymethyl-3,7,11-trimethyl-dodec-6-enyl ester 
• 646519-59-7 2,2-dimethyl-propionic acid (3S,6E)-8-bromo-3,7-dimethyl-oct-6-enyl ester 
• 646519-60-0 (2S)-(2-methoxymethoxymethyl-3-methyl-butane-1-sulfonyl)-benzene 
• 298713-10-7 2,2-dimethyl propionic acid (3S,10S,6E)-10-hydroxymethyl-3,7,11-trimethyl-dodec-6-enyl ester 
• 646519-58-6 2,2-dimethyl-propionic acid (3S,6E)-8-hydroxy-3,7-dimethyl-oct-6-enyl ester 

Downstream Products

• 646519-67-7 (6S,13S,2Z,9E)-15-benzenesulfinyl-13-isopropyl-6,10-dimethyl-4,14-dioxo-pentadeca-2,9-dienoic acid methyl ester 
• 646519-68-8 (6S,13S,2E,9E)-15-benzenesulfinyl-13-isopropyl-6,10-dimethyl-4,14-dioxo-pentadeca-2,9-dienoic acid methyl ester 
• 646519-66-6 (6S,13S,2Z,9E)-15-benzenesulfinyl-4-hydroxy-13-isopropyl-6,10-dimethyl-14-oxo-pentadeca-2,9-dienoic acid methyl ester 
• 646519-65-5 (6S,13S,9E)-15-benzenesulfinyl-4-hydroxy-13-isopropyl-6,10-dimethyl-14-oxo-pentadec-9-en-2-ynoic acid methyl ester 
• 646519-72-4 (E)-(1R,2S,4S,11S)-2-((R)-Benzenesulfinyl)-4-isopropyl-7,11-dimethyl-3,13-dioxo-cyclotetradec-7-enecarboxylic acid methyl ester 
• 298713-15-2 (6E)-(3S,10S)-1-benzenesulfinyl-6,10-dimethyl-3-isopropyl-6,13-tetradecadiene-2,12-dione 
• 298713-14-1 (3S,10S,6E)-12-benzenesulfinyl-10-isopropyl-3,7-dimethyl-11-oxo-dodec-6-enal 

Relevant academic research and scientific papers

Pyranophane Transannular Diels-Alder Approach to (+)-Chatancin: A Biomimetic Asymmetric Total Synthesis

An asymmetric total synthesis of (+)-chatancin was achieved via a transannular Diels-Alder (TADA) reaction of an in situ generated macrocyclic pyranophane pseudobase. The presented route constitutes the second of two proposed biosynthetic pathways that in

Transannular Diels-Alder studies on the asymmetric total synthesis of chatancin: the pyranophane approach.

[reaction: see text] A pathway is proposed for the biosynthesis of (+)-chatancin and (+)-sarcophytin linking these tetracycles to cembranoids by a pyranophane transannular Diels-Alder reaction. Preliminary synthetic results in this direction to reach macr