298713-15-2Relevant articles and documents
Transannular Diels-Alder studies on the asymmetric total synthesis of chatancin: the pyranophane approach.
Toro,L'Heureux,Deslongchamps
, p. 2737 - 2740 (2000)
[reaction: see text] A pathway is proposed for the biosynthesis of (+)-chatancin and (+)-sarcophytin linking these tetracycles to cembranoids by a pyranophane transannular Diels-Alder reaction. Preliminary synthetic results in this direction to reach macr