29879-69-4Relevant academic research and scientific papers
PROCESS FOR THE ASYMMETRIC HYDROGENATION OF IMIDES
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Page/Page column 46, (2010/12/31)
The present disclosure provides a process for the mono-reduction of one or more imide moieties in a compound comprising contacting the compound with hydrogen gas and a catalyst comprising a transition metal hydride in the presence of a base, under conditi
The photodecarboxylative addition of carboxylates to phthalimides: Scope and limitations
Oelgemoeller, Michael,Cygon, Peter,Lex, Johann,Griesbeck, Axel G.
, p. 669 - 684 (2007/10/03)
Intermolecular photoinduced decarboxylative additions of a series of alkylcarboxylates to N-substituted phthalimides gave the corresponding hydroxyphthalimidines in moderate to high yields of 39-89%. The potassium salt of 1-adamantanecarboxylic acid predominately underwent simple decarboxylation when irradiated in the presence of N-methylphthalimide. In case of phthalimides carrying suitable leaving groups within the N-side chain, decarboxylation, retro-Aldol cleavage or decarbonylation preceded the intermolecular addition step.
