29887-38-5

Basic information

• Product Name: artemisiaalcohol,3,3,6-trimethyl-1,5-heptadien-4-ol
• Synonyms: artemisiaalcohol,3,3,6-trimethyl-1,5-heptadien-4-ol;(S)-3,3,6-Trimethyl-1,5-heptadien-4-ol;1,5-Heptadien-4-ol, 3,3,6-trimethyl-, (S)-
• CAS NO: 29887-38-5
• Molecular Formula: C₁₀H₁₈O
• Molecular Weight: 0
• Mol File: 29887-38-5.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 214.3°Cat760mmHg
• Flash Point: 78.5°C
• Appearance: /
• Density: 0.856g/cm³
• CAS DataBase Reference: artemisiaalcohol,3,3,6-trimethyl-1,5-heptadien-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: artemisiaalcohol,3,3,6-trimethyl-1,5-heptadien-4-ol(29887-38-5)
• EPA Substance Registry System: artemisiaalcohol,3,3,6-trimethyl-1,5-heptadien-4-ol(29887-38-5)

Safety Data

• Hazardous Substances Data: 29887-38-5(Hazardous Substances Data)

Upstream product

• 870-63-3 prenyl bromide 
• 107-86-8 3,3-dimethyl acrylaldehyde 
• 141550-13-2 4,4,5,5-tetramethyl-2-(3-methylbut-2-enyl)-1,3,2-dioxaborolane 
• 1187817-21-5 4,4,5,5-tetramethyl-2-(3-methylbut-3-en-1-yl)-1,3,2-dioxaborolane 
• 29917-94-0 2-methylprop-1-enyllithium 
• 122016-68-6 (3-Methyl-but-2-enyloxymethanesulfonyl)-benzene 
• 89487-33-2 prenylmagnesium bromide 
• 72863-21-9 (dimethyl-1,1 propene-2 yl) sulfonyl-1 methyl-4 benzene 
• 5362-50-5 4-methyl-3-penten-1-al 
• 14309-15-0 phenyl prenyl ether 
• 26902-25-0 3-methyl-1-(3-methylbut-2-enyloxy)but-2-ene 
• 3465-88-1 (-)-4-acetoxy-3,3,6-trimethyl-hepta-1,5-diene 
• 556-82-1 3-methyl-2-buten-1-ol 
• 546-49-6 artemisia ketone 

Downstream Products

• 546-49-6 artemisia ketone 
• 110490-36-3 3,5-dinitro-benzoic acid-(1-isobutyl-2,2-dimethyl-butyl ester) 
• 107414-11-9 3,5-dinitro-benzoic acid-(3-methyl-1-tert-pentyl-but-2-enyl ester) 
• 107821-18-1 (+/-)-3c-(1,1-dimethyl-allyl)-5-methyl-cyclohex-4-ene-1r,2c-dicarboxylic acid 
• 29548-02-5 2,5,5-trimethyl-1,3,6-heptatriene 

Relevant articles and documents

Nickel-catalyzed double bond transposition of alkenyl boronates for in situ syn-selective allylboration reactions

The transposition of a homoallyl pinacol boronic ester was realized by a highly reactive nickel-catalyst system comprising NiCl2(dppp), zinc powder, ZnI2, and Ph2PH. The in situ generated Z-crotyl pinacol boronic esters were reacted with various aldehydes to form syn-homoallylic alcohols in high diastereoselectivities. The present nickel-catalyzed reaction is complementary to the iridium-catalyzed transposition reported by Murakami leading to the corresponding anti-homoallylic alcohols. Also, the multiple transposition of pentenyl pinacol boronic ester was realized.

Barbier-type allylation of carbonyl compounds and imines with metallic cadmium

Cadmium mediated allylation of a variety of carbonyl compounds and imines in a Cd/Bu4NBr/THF system afforded excellent yields of the corresponding homoallylic alcohols and amines under very mild reaction conditions.

UN EQUIVALENT SYNTHETIQUE CHIRAL DU PRENAL, LE FORMYL-TRIMETHYLENEMETHANE(FER)TRICARBONYLE. SYNTHESE DU (R)-(-)-IPSDIENOL

Formyl-TMM (Iron)tricarbonyl 3 reacts with a high diastereoselectivity with organozinc derivatives to Iron stabilized TMM-alcohols.These are decomplexed, under partial hydrogenation, by photolysis in acetic acid to give allylic and homoallylic isoprenoic alcohols.Starting from the optically active complex (+)-3, this allows a rapid synthesis of (R)-(-)-Ipsdienol of high ee.