72863-21-9Relevant articles and documents
A General Photocatalytic Route to Prenylation
Rathnayake, Manjula D.,Weaver, Jimmie D.
supporting information, p. 1433 - 1438 (2019/06/13)
Prenylation is an essential reaction on which nature relies to modify properties of molecules and build terpenoids, but remains a challenging chemical reaction. Aiming to capitalize on recent advances in photocatalysis to easily and cleanly generate a broad range of carbon based radicals, we have developed a prenyl transfer reagent that is captured by transiently generated radicals. The reagent can be made in bulk, is bench stable, and broadly applicable such that it can be used with existing photocatalytic methods with very few changes to reaction conditions. Ultimately, this provides a true drop-in solution for prenylation, expanding the scope of substrates that can be readily prenylated.
Selective C - S bond formation via Fe-catalyzed allylic substitution
Jegelka, Markus,Plietker, Bernd
supporting information; experimental part, p. 3462 - 3465 (2009/12/05)
In contrast to the formation of C - O and C - N bonds it was only recently that the selective C - S bond formation by means of transition metal complexes moved more into the center of research. This is somewhat surprising given the fact that the sulfur at
Preparation of some Allylic Sulphones; Base-catalysed Isomerisation and Deuteriation of Cyclohex-2-enyl p-Tolyl Sulphones
Knight, Derek J.,Lin, Peter,Russell, Simon T.,Whitham, Gordon H.
, p. 2701 - 2706 (2007/10/02)
A summary of the methods used in the preparation of a range of allylic sulphones is given.In the case of the conformationally biased sulphones (5) and (6) stereospecific preparation from the cis- and trans-5-t-butylcyclohex-2-en-1-ols was achieved by rear
