29947-32-8Relevant academic research and scientific papers
Terarylenes as Photoactivatable Hydride Donors
Martin, Colin J.,Minamide, Miho,Dela Cruz Calupitan, Jan Patrick,Asato, Ryosuke,Kuno, Jumpei,Nakashima, Takuya,Rapenne, Gwéna?l,Kawai, Tsuyoshi
, p. 13700 - 13706 (2018)
Terarylene frameworks containing benzothiazole as a photoprecursor of hydride donors are presented. We here report on two new scaffolds along with their photoreactivity in solution. Through use of selected external oxidants, the photogeneration of hydride donors is monitored using UV-visible, NMR, and TEM methods. As a proof-of-concept, photogeneration of hydride in the presence of Ag+ gave rise to the formation of Ag nanoparticles.
Pd-Catalyzed Decarbonylative C?H Coupling of Azoles and Aromatic Esters
Matsushita, Kaoru,Takise, Ryosuke,Hisada, Tomoya,Suzuki, Shin,Isshiki, Ryota,Itami, Kenichiro,Muto, Kei,Yamaguchi, Junichiro
supporting information, p. 2393 - 2396 (2018/05/30)
A decarbonylative C?H coupling of azoles and aromatic esters by palladium catalysis is described. Our previously reported Ni-catalyzed C?H coupling of azoles and aromatic esters has a significant drawback regarding the substrate scope. Herein, we employ p
