3002-30-0

Basic information

• Product Name: methyl 9H-fluorene-9-carboxylate
• Synonyms: methyl 9H-fluorene-9-carboxylate;9H-Fluorene-9-carboxylic acid methyl;9H-Fluorene-9-carboxylic acid methyl ester
• CAS NO: 3002-30-0
• Molecular Formula: C₁₅H₁₂O₂
• Molecular Weight: 224.25
• Mol File: 3002-30-0.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 353.1°Cat760mmHg
• Flash Point: 161°C
• Appearance: /
• Density: 1.206g/cm³
• Vapor Pressure: 3.68E-05mmHg at 25°C
• Refractive Index: 1.613
• Storage Temp.: -20°C Freezer
• Solubility: Benzene; Toluene; DMSO; Dichloroform; Chloroform; Ethyl Acetate
• CAS DataBase Reference: methyl 9H-fluorene-9-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 9H-fluorene-9-carboxylate(3002-30-0)
• EPA Substance Registry System: methyl 9H-fluorene-9-carboxylate(3002-30-0)

Safety Data

• Hazardous Substances Data: 3002-30-0(Hazardous Substances Data)

Usage

Uses

Methyl Fluorene-9-carboxylic Acid Ester is an intermediate used in the synthesis of 2-Methylfluoranthene (M305305), which is an environmental pollutant that causes oxidative DNA damage in humans.

InChI:InChI=1/C15H12O2/c1-17-15(16)14-12-8-4-2-6-10(12)11-7-3-5-9-13(11)14/h2-9,14H,1H3

Upstream product

• 67-56-1 methanol 
• 76-89-1 methyl benzilate 
• 38727-30-9 4-Trifluormethyl-nonafluordiphenylamin 
• 3756-37-4 2,2',3,3',4,5,5',6,6'-nonafluoro-4'-bromodiphenylamine 
• 28078-83-3 N-pentafluorophenylbenzamide 
• 19364-92-2 2,3,4,5,6-pentafluoro-N-(pentafluorophenyl)benzamide 
• 38252-93-6 α-methoxycarbonyldiphenylmethyl cation 
• 80588-64-3 N-(2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl)benzamide 
• 80588-40-5 4-chlorononafluorodiphenylamine 
• 80588-44-9 Pentafluorophenyl-(2,4,6-trichloro-3,5-difluoro-phenyl)-amine 

Downstream Products

• 102448-22-6 9-Cyclohexyl-fluorencarbonsaeure-(9)-methylester 
• 745829-85-0 9-(3-oxo-3-phenyl-propyl)-fluorene-9-carboxylic acid methyl ester 
• 102171-51-7 9-butyl-9-methoxycarbonylfluorene 
• 62731-52-6 9-Methylfluoren-9-carbonsaeureethylester 
• 6328-76-3 9-Brom-9-fluorencarbonsaeure-methylester 
• 32501-33-0 methyl 9-ethyl-9-fluorenecarboxylate 
• 101789-51-9 methyl 9-n-propyl-9-fluorenecarboxylate 
• 7471-95-6 9H-fluorene-9-carboxamide 
• 102593-66-8 9-phenacyl-fluorene-9-carboxylic acid methyl ester 
• 67-56-1 methanol 
• 57643-28-4 9-methoxycarbonylfluorene potassium salt 
• 22909-50-8 2-chlorofluorene-9-carboxylic acid methyl ester 
• 67459-64-7 Spiro-2'-on 
• 121721-39-9 methyl 9-pentafluorophenylfluorene-9-carboxylate 

Relevant articles and documents

EQUILIBRIUM NH ACIDITY OF POLYFLUOROALKYL-CONTAINIG COMPOUNDS

The pK vvalues of NH acids containing a polyfluoroaryl group at the α position to the acid center (polyfluoroalkyl- and diarylamines, polyfluoroanilines) with reference to 9-phenylfluorene were obtained by transmetallation in dimethyl sulfoxide (cation potassium).The acidifying effects of the C6F5, β-C10F7, and C5F4N (tetrafluoro-4-pyridyl) groups were evaluated.The acidity of the C6F5NHR compounds correlates satisfactorily with the parameters of the 19F NMR spectra of the N-anions or NH acids and with the ?* constants of the substituent R.In the series of compounds p-RC6F4NHC6F5 and p-RC6F4NH(O)C6H5 a correlation is observed between the pK values and the Hammett constants of the substituent R.In most cases the conduction of the effect of the substituent R in these series to the NH reaction center is analogous with that in the corresponding unfluorinated series.