30038-32-5

Basic information

• Product Name: Benzene, 1,1'-methylenebis[2,4,5-trimethoxy-
• CAS NO: 30038-32-5
• Molecular Formula: C19H24O6
• Molecular Weight: 348.396
• Mol File: 30038-32-5.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-methylenebis[2,4,5-trimethoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-methylenebis[2,4,5-trimethoxy-(30038-32-5)
• EPA Substance Registry System: Benzene, 1,1'-methylenebis[2,4,5-trimethoxy-(30038-32-5)

Safety Data

• Hazardous Substances Data: 30038-32-5(Hazardous Substances Data)

Upstream product

• 93-51-6 2-Methoxy-4-methylphenol 
• 135-77-3 1,2,4-trimethoxy-benzene 
• 124-38-9 carbon dioxide 
• 2033-89-8 3,4-dimethoxyphenol 
• 83700-81-6 bis-(2,4,5-trimethoxy-phenyl)-acetic acid 
• 42833-66-9 2,4,5-trimethoxybenzoyl chloride 
• 101747-57-3 4,4',5,5'-Tetramethoxy-2,2'-dihydroxy-diphenylmethan 
• 77-78-1 dimethyl sulfate 
• 4460-86-0 asaraldehyde 
• 110047-63-7 bis(2,4,5-trimethoxyphenyl)methanone 
• 30038-31-4 (2,4,5-trimethoxyphenyl)methanol 
• 50-00-0 formaldehyd 

Relevant articles and documents

Acid-Triggered Colorimetric Hydrophobic Benzyl Alcohols for Soluble Tag-Assisted Liquid-Phase Synthesis

Simple screening of acid-triggered reactions of methoxybenzyl alcohols led to the development of a novel colorimetric hydrophobic benzyl alcohol (HBA) tag. HBA tag-3 (14) retained high solubility in less polar solvents and excellent precipitation properti

Br?nsted acid ionic liquids catalyzed Friedel-Crafts Alkylations of electron-rich arenes with aldehydes

Triarylmethanes (TRAMs) and diarylalkanes (DIAAs) are valuable intermediates with wide applications in many fields. TRAMs are usually obtained from the acid-catalysed bisarylation of activated aryl aldehydes. However, the synthesis poses many problems, such as harsh reaction conditions, and the disposal of the excess solvents and/or toxic metal waste. In this study, some functionalized ionic liquids including Br?nsted acid ionic liquids (BAILs) and traditional ionic liquids were designed and synthesized. BAILs catalyzed Friedel-Crafts (F-C) alkylation was applied in this specific reaction for the first time. And the BAILs showed bifunctional properties acting as catalyst and solvent. Research shows that BAILs can be used for catalyzing F-C alkylations of electron-rich arenes with aromatic or aliphatic aldehydes successfully under mild reaction conditions. Furthermore, BAILs containing triflic anion has higher activity than other BAILs and traditional ionic liquids. [HSO 3-pmim][OTf] gets the highest yields in the presence of 20 mol% of BAILs at 40 °C to give the corresponding TRAMs derivatives. After five cycles, the yields remain about 93-97%. Finally, according to IR spectrum and the experimental validation, the aromatic electrophilic substitution reaction was considered to be the possible catalysis mechanisms.

Trifluoromethanesulfonic acid catalyzed Friedel-Crafts alkylations of 1,2,4-trimethoxybenzene with aldehydes or benzylic alcohols

Trifluoromethanesulfonic acid in acetonitrile was found to efficiently catalyze Friedel-Crafts alkylations of 1,2,4-trimethoxybenzene with a variety of simple or functionalized aldehydes to provide di- or triarylmethanes in high yields. The operationally