3018-24-4Relevant articles and documents
Steric control at the wingtip of a bis-N-heterocyclic carbene ligand: Coordination behavior and catalytic responses of its ruthenium compounds
Saha, Sayantani,Ghatak, Tapas,Saha, Biswajit,Doucet, Henri,Bera, Jitendra K.
, p. 5500 - 5505 (2012/11/07)
Changing the N-substituents of a methylene-linked bis-NHC ligand from n-butyl to bulky mesityl shifts ligand coordination from normal/normal to normal/abnormal mode. The mesityl wingtip groups afford [RuII( MesNHC(CH2)NHC