354-31-4Relevant academic research and scientific papers
Gas-phase photodissociation of CF3C(O)Cl between 193 and 280 nm
McGillen, Max R.,Burkholder, James B.
, p. 189 - 194 (2015/10/12)
Product yields were measured in the 296 K photolysis of CF3C(O)Cl at 193, 248, 254, and 280 nm. Br2 was used as a radical scavenger to convert the primary CF3 and CF3CO radical photofragments into stable bromides, CF3Br and CF3C(O)Br, which were quantified along with CO and CF2O using infrared absorption. The stabilized CF3CO radical yield increased with increasing photolysis wavelength from 3Cl quantum yield was determined to be 0.001 at all wavelengths.
Facile conversion of perfluoroacyl fluorides into other acyl halides
Fukaya, Haruhiko,Matsumoto, Tomonori,Hayashi, Eiji,Hayakawa, Yoshio,Abe, Takashi
, p. 915 - 920 (2007/10/03)
Nine perfluoroacyl fluorides underwent halogen exchange when treated with anhydrous lithium halides to give acyl chlorides, bromides and iodides in high yields. The temperature dependence of this reaction is described. In the reaction with perfluorodiacyl fluoride, the diacyl halides possessing different acyl halide-groups were also produced. Of the alkaline metal salts used halogen exchange was successful only with lithium salts because of the interaction between lithium and fluorine.
