30189-91-4

Basic information

• Product Name: N-dodecyl-N-methylaniline
• Synonyms: N-dodecyl-N-methylaniline;Dodecylmethylphenylamine
• CAS NO: 30189-91-4
• Molecular Formula: C₁₉H₃₃N
• Molecular Weight: 275.47202
• EINECS: 250-087-6
• Mol File: 30189-91-4.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 370.2°Cat760mmHg
• Flash Point: 150.2°C
• Appearance: /
• Density: 0.891g/cm³
• Vapor Pressure: 1.12E-05mmHg at 25°C
• Refractive Index: 1.504
• CAS DataBase Reference: N-dodecyl-N-methylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-dodecyl-N-methylaniline(30189-91-4)
• EPA Substance Registry System: N-dodecyl-N-methylaniline(30189-91-4)

Safety Data

• Hazardous Substances Data: 30189-91-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C19H33N/c1-3-4-5-6-7-8-9-10-11-15-18-20(2)19-16-13-12-14-17-19/h12-14,16-17H,3-11,15,18H2,1-2H3

Upstream product

• 143-15-7 1-dodecylbromide 
• 100-61-8 N-methylaniline 
• 112-53-8 1-dodecyl alcohol 
• 121-69-7 N,N-dimethyl-aniline 
• 2437-25-4 undecyl cyanide 
• 112-41-4 1-dodecene 
• 614-30-2 N-methyl-N-phenyl-benzenemethanamine 

Downstream Products

• 55586-74-8 4-(Dodecyl-methyl-amino)-benzaldehyde 
• 80631-76-1 Dodecyl-methyl-[4-(4-nitro-phenylazo)-phenyl]-amine 

Relevant articles and documents

First Example of a Pyrylium Salt Dimerisation in Solution

A pyrylium salt is capable of forming dimers in non-polar solvents at room temperature.The dimer, corresponding to a head-to-tail configuration in which the monomer dipole moments are parallel, has been characterized by its electronic absorption spectra, fluorescence spectra and its fluorescence lifetime.The dimer-monomer equilibrium constant is found to be 2.7 * 105 dm3 mol-1.

Visible light-induced N-methyl activation of unsymmetric tertiary amines

In the presence of methylene group, selective N-methyl activation of tertiary amines has been accomplished with the aid of visible light using organic photocatalyst under air. This protocol explores numerous aliphatic and aromatic substituted tetra-hydroquinoline analogues from various tertiary amines and maleimides. Furthermore, this approach was applied to activate the methyl group of N-methyl carbazole to generate the biologically active molecule.

Formal anti-Markovnikov hydroamination of terminal olefins

A new strategy to access linear amines from terminal olefin precursors is reported. This two-step, one-pot hydroamination methodology employs sequential oxidation and reduction catalytic cycles. The formal hydroamination transformation proceeds with excellent regioselectivity, and only the anti-Markovnikov product is observed. Up to 70% yield can be obtained from styrenes or aliphatic olefins and either primary or secondary aromatic amines. Additionally, the scope is broad with respect to the olefin and accommodates a variety of functionalities; we demonstrate that amines with removable aryl protecting groups may be utilized to allow access to a more diverse array of hydroamination adducts.