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2437-25-4

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2437-25-4 Usage

Chemical Properties

CLEAR YELLOW LIQUID

Synthesis Reference(s)

Tetrahedron Letters, 28, p. 295, 1987 DOI: 10.1016/S0040-4039(00)95711-3

Flammability and Explosibility

Notclassified

Check Digit Verification of cas no

The CAS Registry Mumber 2437-25-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,4,3 and 7 respectively; the second part has 2 digits, 2 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 2437-25:
(6*2)+(5*4)+(4*3)+(3*7)+(2*2)+(1*5)=74
74 % 10 = 4
So 2437-25-4 is a valid CAS Registry Number.
InChI:InChI=1/C12H23N/c1-2-3-4-5-6-7-8-9-10-11-12-13/h2-11H2,1H3

2437-25-4 Well-known Company Product Price

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  • Alfa Aesar

  • (A19038)  Dodecanonitrile, 98%   

  • 2437-25-4

  • 10g

  • 286.0CNY

  • Detail
  • Alfa Aesar

  • (A19038)  Dodecanonitrile, 98%   

  • 2437-25-4

  • 50g

  • 1121.0CNY

  • Detail
  • Alfa Aesar

  • (A19038)  Dodecanonitrile, 98%   

  • 2437-25-4

  • 250g

  • 5024.0CNY

  • Detail

2437-25-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name Dodecanenitrile

1.2 Other means of identification

Product number -
Other names n-Undecyl cyanide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Intermediates,Surface active agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2437-25-4 SDS

2437-25-4Relevant articles and documents

Fatty acid methyl esters into nitriles: Acid-base properties for enhanced catalysts

Mekki-Berrada,Bennici,Gillet,Couturier,Dubois,Auroux

, p. 30 - 37 (2013)

Fatty nitriles have lately become of interest in the frame of biofuels or for the valorization of the oil part of biomass as fine chemicals such as polymers. The production of long-chain fatty nitriles by direct reaction of esters with ammonia has however not been academically extensively studied, although several catalysts were developed and published in patents. Acid-base features are implicitly considered as leading the catalysis of this reaction, but no direct correlation was investigated with any nature or number of acidic or basic sites. The present study aims at understanding which sites are responsible of this reaction and thus how to design better catalysts. Strong acidity correlates at 300 C for ester conversion and nitrile yield, suggesting a common nature of the reaction among all kinds of catalysts. An upper strength limit, over which undesirable side-products appear, was evaluated, and the factors influencing the production of N-methyl amide were analyzed.

Iodine Promoted Conversion of Esters to Nitriles and Ketones under Metal-Free Conditions

Xiao, Jing,Guo, Fengzhe,Li, Yinfeng,Li, Fangshao,Li, Qiang,Tang, Zi-Long

, p. 2028 - 2035 (2021/02/03)

We report a novel strategy to prepare valuable nitriles and ketones through the conversion of esters under metal-free conditions. By using the I2/PCl3 system, various substrates including aliphatic and aromatic esters could react with acetonitrile and arenes to afford the desired products in good to excellent yields. This method is compatible with a number of functional groups and provides a simple and practical approach for the synthesis of nitrile compounds and aryl ketones.

Facile dehydration of primary amides to nitriles catalyzed by lead salts: The anionic ligand matters

Ruan, Shixiang,Ruan, Jiancheng,Chen, Xinzhi,Zhou, Shaodong

, (2020/12/09)

The synthesis of nitrile under mild conditions was achieved via dehydration of primary amide using lead salts as catalyst. The reaction processes were intensified by not only adding surfactant but also continuously removing the only by-product, water from the system. Both aliphatic and aromatic nitriles can be prepared in this manner with moderate to excellent yields. The reaction mechanisms were obtained with high-level quantum chemical calculations, and the crucial role the anionic ligand plays in the transformations were revealed.

Synthesis, characterization, catalytic and biological application of half-sandwich ruthenium complexes bearing hemilabile (κ2-: C, S)-thioether-functionalised NHC ligands

Achard, Thierry,Bellemin-Laponnaz, Stéphane,Chen, Weiguang,Egly, Julien,Maisse-Francois, Aline,Poblador-Bahamonde, Amalia I.

supporting information, p. 3243 - 3252 (2020/03/19)

A series of cationic Ru(ii)(η6-p-cymene) complexes with thioether-functionalised N-heterocyclic carbene ligands have been prepared and fully characterized. Steric and electronic influence of the R thioether substituent on the coordination of the sulfur atom was investigated. The molecular structure of three of them has been determined by means of X-ray diffractrometry and confirmed the bidentate (κ2-C,S) coordination mode of the ligand. Interestingly, only a single diastereomer, as an enantiomeric couple, was observed in the solid state for complexes 1c, 1i and 1j. DFT calculations established a low energy inversion barrier between the two diastereomers through a sulfur pyramidal inversion pathway with R donating group while a dissociative/associative mechanism is more likely with R substituents that contain electron withdrawing group, thus suggesting that the only species observed by the 1H-NMR correspond to an average resonance position of a fluxional mixtures of isomers. All these complexes were found to catalyse the oxydant-free double dehydrogenation of primary amine into nitrile. Ru complex bearing NHC-functionalised S-tBu group was further investigated in a wide range of amines and was found more selective for alkyl amine substrates than for benzylamine derivatives. Finally, preliminary results of the biological effects on various human cancer cells of four selected Ru complexes are reported.

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