30289-16-8

Basic information

• Product Name: (diethylamino)({[(1Z)-1-phenylethylidene]amino}oxy)methanone
• CAS NO: 30289-16-8
• Molecular Formula: C₁₃H₁₈N₂O₂
• Molecular Weight: 234.2942
• Mol File: 30289-16-8.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 316.913°C at 760 mmHg
• Flash Point: 145.464°C
• Density: 1.018g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.508
• CAS DataBase Reference: (diethylamino)({[(1Z)-1-phenylethylidene]amino}oxy)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (diethylamino)({[(1Z)-1-phenylethylidene]amino}oxy)methanone(30289-16-8)
• EPA Substance Registry System: (diethylamino)({[(1Z)-1-phenylethylidene]amino}oxy)methanone(30289-16-8)

Safety Data

• Hazardous Substances Data: 30289-16-8(Hazardous Substances Data)

Usage

General Description

The chemical compound "(diethylamino)({[(1Z)-1-phenylethylidene]amino}oxy)methanone" is a complex organic compound that contains diethylamino and phenylethylidene groups. Its chemical structure consists of a ketone group (methanone) attached to a diethylamino group and an oxime group formed by the condensation of a phenylethylidene and diethylamino groups. (diethylamino)({[(1Z)-1-phenylethylidene]amino}oxy)methanone may have potential applications in organic synthesis, pharmaceuticals, or other industrial processes due to its unique structure and functional groups. Further research and testing are needed to fully understand its potential uses and properties.

Upstream product

• 613-91-2 acetophenone oxime 
• 61985-24-8 N,N-diethyl-1H-imidazole-1-carboxamide 

Downstream Products

• 1854-28-0 benzoyloxy radical 
• 109-89-7 diethylamine 
• 729-43-1 acetophenonazine 
• 13280-20-1 1-phenylethanimine 
• 98-86-2 acetophenone 

Relevant articles and documents

Dissociation or cyclization: Options for a triad of radicals released from oxime carbamates

A set of oxime carbamates having N-alkyl and N,N-dialkyl substituents were prepared via carbonyldiimidazole intermediates. It was shown by EPR spectroscopy that they underwent clean homolysis of their N-O bonds upon UV photolysis. During photolysis of acetophenone O-allylcarbamoyl oxime, the corresponding oxazolidin-2-onylmethyl radical was detected by EPR spectroscopy, providing the first evidence that N-monosubstituted carbamoyloxyl radicals can hold their structural integrity. N,N-Disubstituted carbamoyloxyl radicals dissociated rapidly at the lowest accessible temperatures. Above room temperature, both types of oxime carbamate acted as selective new precursors for aminyl and iminyl radicals. Rate parameters were measured for 5-exo cyclization of N-benzyl-N-pent-4-enylaminyl radicals; the rate constant was smaller than for C-centered and O-centered analogues. Oxime carbamates derived from the volatile diethylamine afforded aryliminyl radicals that proved convenient for phenanthridine preparations.