30358-01-1Relevant academic research and scientific papers
Zinc base assisted amination of 2-chloropyrimidines by aniline derivatives at room temperature
Delvos, Lukas B.,Begouin, Jeanne-Marie,Gosmini, Corinne
supporting information; experimental part, p. 2325 - 2328 (2011/11/06)
The amination of 2-chloropyrimidines was performed with several aniline derivatives in the presence of tolylzinc bromide as a base. The organozinc compound has a profound effect on the reactivity of the amines, so that the reaction takes place at room tem
A novel hydride-mediated reductive rearrangement of amide: a facile synthesis of pyrimidyl and triazinyl amines
Chen, Xiang,Wu, Jun,Shang, Zhicai,Chen, Meifeng,Sun, Yanping,Lv, Jing,Lei, Meikang,Zhang, Peizhi
, p. 495 - 499 (2008/04/13)
LiAlH4 and NaBH4 were found to mediate the conversion of 2-(pyrimidyl-2-ylsulfanyl)-N-arylbenzamides and 2-(triazinyl-2-ylsulfanyl)-N-arylbenzamides into pyrimidyl and triazinyl amines under notably mild conditions via a novel reductive rearrangement mechanism. These reactions invent a new route to prepare amines, which are a kind of important biologically active compounds and provide the first insight into a novel hydride-promoted reductive rearrangement of amides.
Synthesis, structure, and dynamic behavior in solution of arylamino-1,3,5-triazines. 1. Unsymmetrically substituted arylamino-1,3,5- triazines
Belyakov,Shatin,Strelenko
, p. 2441 - 2451 (2007/10/03)
Ten unsymmetrically substituted arylamino-1,3,5-triazines were synthesized and studied by dynamic NMR spectroscopy. The free energies of the hindered rotation ΔG≠ are in 59-77 kJ mol-1 range. Using difference-mode NOE NMR experiments
The configuration of N-alkyl-anilino-s-triazine derivatives
Wu, Zuwang,Yang, Haiyan,Sun, Zhonghai
, p. 534 - 535 (2007/10/03)
The alkyl group on the imino bridge of heterobifunctional reactive dyes plays a major role in improving the dyeing properties. The configurations of a pair of model compounds 2,4-dimethoxy-6-anilino-s-triazine and 2,4-dimethoxy-6-(N-metyl-anilino)-s-triaz
MANGANESE DIOXIDE OXIDATION OF HYDROXYAMINO-sym-TRIAZINES
Sedova. V. F.,Shkurko, O. P.
, p. 593 - 597 (2007/10/02)
The hydroxyamino group in sym-triazines is readily oxidized by the action of manganese dioxide.The stability of the nitrosotriazines formed in this oxidation depends on the electron donor properties of the other substituents in the molecule.
