3042-63-5

Basic information

• Product Name: β-(4-methylbenzyl)naphthalene
• Synonyms: β-(4-methylbenzyl)naphthalene
• CAS NO: 3042-63-5
• Molecular Weight: 232.325
• Mol File: 3042-63-5.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: β-(4-methylbenzyl)naphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: β-(4-methylbenzyl)naphthalene(3042-63-5)
• EPA Substance Registry System: β-(4-methylbenzyl)naphthalene(3042-63-5)

Safety Data

• Hazardous Substances Data: 3042-63-5(Hazardous Substances Data)

Upstream product

• 53006-28-3 2-[1-p-Tolyl-meth-(E)-ylidene]-1,2,3,4-tetrahydro-naphthalen-1-ol 
• 1076-67-1 2-(mercaptomethyl)naphthalene 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 108-88-3 toluene 
• 1592-38-7 2-Naphthalenemethanol 
• 21983-00-6 4-methylbenzylboronic acid 
• 17666-88-5 1-(naphthalen-2-yl)butan-1-one 
• 19350-74-4 2-naphthaldehyde tosylhydrazone 
• 5720-05-8 4-methylphenylboronic acid 
• 66-99-9 β-naphthaldehyde 
• 106-38-7 para-bromotoluene 
• 42101-92-8 2-naphthylmethyl methyl ether 
• 13922-41-3 1-Naphthylboronic acid 
• 104-82-5 4-Methylbenzyl chloride 

Downstream Products

• 70557-78-7 2-(4-methylbenzyl)-1,4-naphthoquinone 

Relevant articles and documents

Arylketones as Aryl Donors in Palladium-Catalyzed Suzuki-Miyaura Couplings

Herein, we report the arylation, alkylation, and alkenylation of aryl ketones via a palladium-catalyzed Suzuki-Miyaura cross-coupling reaction. The use of the pyridine-oxazoline ligand is the key to the cleavage of the unstrained C-C bond. The late-stage arylation of aryl ketones derived from drugs and natural products demonstrated the synthetic utility of this protocol.

Synthetic method of diarylmethanes

The invention discloses a synthetic method of diarylmethanes. The method is characterized in that benzyl pseudohalide and aromatic boric acid are reacted in an organic solvent under alkaline condition. The method employs easily available raw materials, conversion is realized under effect of no transition metal catalysis, water-free and oxygen-free are not required, Lewis acid catalysis is not required, the method has wide substrate universality, and various substituted diarylmethanes can be synthesized by the method.

Practical Cross-Coupling between O-Based Electrophiles and Aryl Bromides via Ni Catalysis

Cross-coupling of various O-based electrophiles with aryl bromides was developed through Ni-catalyzed C-O activation in the presence of magnesium. Beside carboxylates, carbamates, and ethers, phenols exhibited excellent reactivity under modified conditions. This chemistry was featured as a simple and environmentally benign process with low catalyst loading and easy manipulations. The method exhibited broad substrate scopes.