304459-79-8

Upstream product

• 766-94-9 vinyl phenyl ether 
• 143064-49-7 1-(Ethoxy-phenyl-methyl)-1H-benzotriazole 

Downstream Products

• 202396-30-3 1-(3-Ethoxy-1-phenoxy-3-phenyl-1-trimethylsilanyl-propyl)-1H-benzotriazole 
• 202396-32-5 2-Benzotriazol-1-yl-4-ethoxy-2-phenoxy-4,N-diphenyl-thiobutyramide 
• 202396-14-3 1-[1-(2-Ethoxy-2-phenyl-ethyl)-1-phenoxy-heptyl]-1H-benzotriazole 
• 107486-95-3 (E)-3-phenyl-1-trimethylsilyl-2-propen-1-one 
• 202396-35-8 2-Benzotriazol-1-yl-4-ethoxy-N-isopropyl-2-phenoxy-4-phenyl-butyramide 
• 304459-80-1 1-(3-Ethoxy-1-methyl-1-phenoxy-3-phenyl-propyl)-1H-benzotriazole 
• 202396-12-1 1-(3-Ethoxy-1-ethyl-1-phenoxy-3-phenyl-propyl)-1H-benzotriazole 
• 202396-24-5 2-Benzotriazol-1-yl-4-ethoxy-2-phenoxy-1,4-diphenyl-butan-1-ol 
• 202396-28-9 (2-Benzotriazol-1-yl-4-ethoxy-2-phenoxy-4-phenyl-1-p-tolyl-butyl)-phenyl-amine 
• 202396-18-7 2-Benzotriazol-1-yl-4-ethoxy-2-phenoxy-1,1,4-triphenyl-butan-1-ol 
• 202396-19-8 1-(1-Benzotriazol-1-yl-3-ethoxy-1-phenoxy-3-phenyl-propyl)-cyclohexanol 

Relevant academic research and scientific papers

Synthesis of β-Alkoxy Ketones and α′-Functionalized β-Alkoxy Ketones Utilizing Benzotriazole-Stabilized Acyl Anion Synthons

1-(α-Alkoxyalkyl)benzotriazoles 1a-d add to phenyl vinyl ether to form key intermediates 4a-d, which readily undergo lithiation and subsequent trapping by a variety of electrophiles to give the expected substituted derivatives 7a-d, 9a-c, 11, 13, 15, and 18 in high yields. Subsequent hydrolysis of these compounds provides a novel high-yield acyl anion synthon approach for the synthesis of β-alkoxy ketones 8 or α′-functionalized β-alkoxy ketones 10, 12, 14, 16, and 19 by short procedures from readily available starting materials.