305834-20-2

Upstream product

• 55287-54-2 3,4-di-O-benzyl-2-acetamido-2-desoxy-α-benzyl-D-glucopyranoside 
• 13343-62-9 benzyl 2-acetamido-2-deoxy-α-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 33493-71-9 benzyl 2-acetamido-2-deoxy-6-O-trityl-α-D-gluco-pyranoside 
• 55287-53-1 benzyl 2-acetamido-3,4-di-O-benzyl-2-deoxy-6-O-trityl-α-D-gluco-pyranoside 

Downstream Products

• 305834-25-7 5-acetamido-3,4-di-O-benzyl-1,2,5-trideoxy-L-xylo-hex-1-enitol 

Relevant academic research and scientific papers

The cobalt-catalyzed oxygenative radical route from hexopyranosides to carbapentofuranoses

Cobalt-catalyzed radical cyclization/oxygenation of various 6-iodohex-1-enitols gave in one step the carbocyclic analogs of pentofuranoses. The reaction was run under very mild conditions and gave moderate to good yields of carbapentofuranoses within a few hours. All the possible 6-iodohex-1-enitol stereoisomers were prepared, and the influence of relative configurations and protecting groups was studied.