30670-21-4Relevant academic research and scientific papers
Regio- and stereospecific cleavage of α,β-epoxysilanes with lithium diphenylphosphide
Cuadrado, Purificacion,Gonzalez - Nogal, Ana M.
, p. 8117 - 8120 (1997)
Silyl epoxides 1a-e react with lithium diphenylphosphide and then with methyl iodide to give vinylphosphonium iodides resulting from α-opening of the epoxide ring and subsequent Peterson elimination. In the same conditions, the E-β-phenyl-α-tert-butyldiph
Regio- and stereospecific cleavage of silyl- and disilylepoxides with lithium diphenylphosphide
Cuadrado, Purificacion,Gonzalez-Nogal, Ana M.,Sarmentero, M. Angeles
, p. 4491 - 4497 (2007/10/03)
Unsubstituted or α- and β-C-substituted silylepoxides react stereospecifically with lithium diphenylphosphide, optionally followed by methylation, to give vinylphosphonium iodides or vinylphosphine oxides resulting from α-opening and silyl enol ethers, vi
